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Soot fouling on exhaust gas recirculation coolers (EGRc) decreases thermal efficiency, implying the unfulfillment of NOx standards, and increases the pressure drop producing the malfunctioning of this device. The characterization of soot is of great interest since soot physico-chemical properties may have a direct influence on the degree of malfunctioning of EGRc. Thus, the combined analysis and interpretation of all the soot physico-chemical features are essential to correctly interpret its behavior when soot is deposited on the EGRc walls. In this context, the aim of this study is the characterization of five different types of diesel soot which were collected from several high pressure EGRc, working at different conditions (engine bench and vehicle). Each soot sample was characterized by means of elemental analysis, specific surface area (BET method), FESEM, FTIR, TGA, GC-MS and UV-visible spectroscopy.

Nowadays, alcohol fuels are of increasing interest as alternative transportation biofuels even in compression ignition engines because they are oxygenated and producible in a sustainable way. In this paper, the experimental research activity was conducted on a single cylinder research engine provided with a modern architecture and properly modified in a dual-fuel (DF) configuration. Looking at ethanol the as one of the future environmental friendly biofuels experimental campaign was aimed to evaluate in detail the effect of the use of the ethanol as port injected fuel in diesel engine on the size, morphology, reactivity and chemical features of the exhaust emitted soot particles. The engine tests were chosen properly in order to represent actual working conditions of an automotive light-duty diesel engine. A proper engine Dual-Fuel calibration was set-up respecting prefixed limits on in-cylinder peak firing pressure, cylinder pressure rise, fuel efficiency and gaseous emissions.