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The effect of legislation in driving towards lower emissions has seen significant changes in injector design, (common- rail) and fuel composition (ULSD). This has led to numerous reports of deposits throughout the vehicle diesel system, filters, tanks, pumps and injectors. In recent examples, deposits internal to the fuel injector on the needle have become prevalent and characterisation of the deposits on the injector needle has become an industry priority. A number of studies have made progress on this but the deposits have proven difficult to fully characterise and often have an ineradicable nature, which makes analysis other than in situ difficult. This paper will describe for the first time the application of a number of surface techniques, in combination which not only provide characterisation data but also the ability to provide cross-sectional lifts out of the sample, which may then be the subject of further analysis.

The determination of size distribution of soot particles and agglomerates in oil samples using a Nanosight LM14 to perform Nanoparticle Tracking Analysis (NTA) is described. This is the first application of the technique to sizing soot-in-oil agglomerates and offers the advantages of relatively high rates of sample analysis and low cost compared to Transmission Electron Microscopy (TEM). Lubricating oil samples were drawn from the sump of automotive diesel engines run under a mix of light duty operating conditions. The oil samples were diluted with heptane before analysing. Results from NTA analysis were compared with the outputs of a more conventional analysis based on Dynamic Light Scattering (DLS). This work shows that soot-in-oil exists as agglomerates with average size of 115 nm. This is also in good agreement with TEM analysis carried out in a previous work. NTA can measure soot particles in polydisperse oil solutions and report the size distribution of soot-in-oil aggregates.