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Technical Paper

Interactions among Fuel Components from Diesel Fuel and Biodiesel

2013-10-14
2013-01-2594
The European diesel fuel specification limits the biodiesel content to 7 %. It is, however, desirable to increase the amount of renewables in the transport sector; therefore blending with a higher biogenic fuel content is of interest. Blending of fuels can lead to chemical reactions between fuel components and may result in undesired products. In detail, aged biodiesel from unsaturated FAME and fossil diesel fuels can form oligomers and precipitations with a maximum in the range of B10 to B20. Precursors are oligomers that can be separated from the biodiesel or the blends in an amount of up to 20 %. These oligomers are soluble in the fuel, but they seem to have potency for chemical reactions with fuel components or the engine oil. To prevent tentative problems in the fuel filter, the injecting system and the combustion process itself, the formation of oligomers should be disabled in blends. Alcohols have been proven and tested to dissolve precipitations in the fuel.
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