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Three jet fuel surrogates were compared against their target fuels in a compression ignited optical engine under a range of start-of-injection temperatures and densities. The jet fuel surrogates are representative of petroleum-based Jet-A POSF-4658, natural gas-derived S-8 POSF-4734 and coal-derived Sasol IPK POSF-5642, and were prepared from a palette of n-dodecane, n-decane, decalin, toluene, iso-octane and iso-cetane. Optical chemiluminescence and liquid penetration length measurements as well as cylinder pressure-based combustion analyses were applied to examine fuel behavior during the injection and combustion process. HCHO* emissions obtained from broadband UV imaging were used as a marker for low temperature reactivity, while 309 nm narrow band filtered imaging was applied to identify the occurrence of OH*, autoignition and high temperature reactivity.

An experimental fuel surrogate validation approach is proposed for a compression ignition application, and applied to validate a Jet-A POSF 4658 fuel surrogate. The approach examines the agreement of both physical and chemical properties of surrogate and target fuels during validation within a real compression-ignition engine environment during four sequential but distinct combustion phases. In-cylinder Mie Scattering measurements are applied to evaporating sprays to compare the behavior of the surrogate, its target fuel, and for reference, n-heptane. Early mixture formation and low temperature reaction behavior were investigated using 2-D broadband chemiluminescence imaging, while high temperature ignition and combustion chemistry were studied using OH chemiluminescence imaging. The optical measurements were combined with cylinder pressure-based combustion analysis, including ignition delay and premixed burn duration, to validate the global behavior of the surrogate.

As engine efficiency targets continue to rise, additional improvements must consider reduction of heat transfer losses. The development of advanced heat transfer models and realistic boundary conditions for simulation based engine design both require accurate in-cylinder wall temperature measurements. A novel dual wavelength infrared diagnostic has been developed to measure in-cylinder surface temperatures with high temporal resolution. The diagnostic has the capability to measure low amplitude, high frequency temperature variations, such as those occurring during the gas exchange process. The dual wavelength ratio method has the benefit of correcting for background scattering reflections and the emission from the optical window itself. The assumption that background effects are relatively constant during an engine cycle is shown to be valid over a range of intake conditions during motoring.

Emissions of Unburned Hydrocarbons (UHC) from diesel engines are a particular concern during the starting process, when after-treatment devices are typically below optimal operating temperatures. Drivability in the subsequent warm-up phase is also impaired by large cyclic fluctuations in mean effective pressure (MEP). This paper discusses in-cylinder wall temperature influence on unburned hydrocarbon emissions and combustion stability during the starting and warm-up process in an optical engine. A laser-induced phosphorescence technique is used for quantitative measurements of in-cylinder wall temperatures just prior to start of injection (SOI), which are correlated to engine out UHC emission mole fractions and combustion phasing during starting sequences over a range of charge densities, at a fixed fueling rate. Squish zone cylinder wall temperature shows significant influence on engine out UHC emissions during the warm-up process.

A means of validating numerical simulations has been developed which utilizes chemiluminescence measurements from an internal combustion engine. By incorporating OH*, CH2O* and CO2* chemiluminescence sub-mechanisms into a detailed n-heptane reaction mechanism, excited species concentration and chemiluminescence light emission were calculated. The modeled line-of-sight chemiluminescence emission allows a direct comparison of simulation results to experimentally measured chemiluminescence images obtained during combustion in an optically accessible compression ignition engine using neat n-heptane fuel. The spray model was calibrated using in-cylinder liquid penetration length Mie scattering measurements taken from the jets of the high-pressure piezo injector.