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This paper reports an experimental and numerical investigation of the spray structure development for pure gasoline fuel and two different ethanol-gasoline blends (10% and 85% ethanol). A numerical methodology has been developed to improve the prediction of the pure and blends fuel spray. The fuel sprays have been simulated by means of a 3D-CFD code, adopting a multi-component approach for the fuel simulations. The vaporization behavior of the real fuel has been improved testing blends of 7 hydrocarbons and a reduced multi-component model has been defined in order to reduce the computational cost of the CFD simulations. Particular care has been also dedicated to the modeling of the atomization and secondary breakup processes occurring to the GDI sprays. The multi-hole jets have been simulated by means of a new atomization approach combined with the Kelvin-Helmholtz/Rayleigh-Taylor hybrid model.