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Among the new combustion concepts envisaged to meet future regulations, the Dual Fuel (DF) concept is considered to be an attractive strategy due to its potential to reduce CO2 emissions and engine-out pollutant emissions levels. A small quantity of high-cetane fuel (Diesel) is injected in the combustion chamber in order to ignite a homogeneous mixture of air and a highly volatile fuel (gasoline in our study). The DF concept has been shown to achieve improved engine thermal efficiency and low engine-out NOx and soot emissions. However, the physical mechanisms controlling DF combustion and in particular, determination of the predominant combustion regime(s) are not yet well understood. In this study, numerical simulations (CFD) and optical engine measurements are used to investigate Dual Fuel combustion.