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Homogeneous charge compression ignition (HCCI) is a promising internal combustion engine concept, but suffers from its high sensitivity to operation conditions and disturbances, such as the intake temperature fluctuation, the load fluctuation or the in-cylinder temperature distribution variation. In this paper, a novel control method is proposed for a port-fuel-injected stoichiometric HCCI engine equipped with variable valve actuation (VVA). A first principle model is developed for controller synthesis with intake valve closing (IVC), exhaust valve closing (EVC), and injected fuel quantity as inputs and combustion timing (CA50), Gross IMEP and Lambda as outputs. The proposed method combines the features of model-based feedforward, decoupling, and active disturbance rejection control (ADRC), named MDDC for short, where the easily modeled cross-coupling and disturbances are compensated directly, while all the remaining uncertainties are estimated and mitigated in real time by ADRC.