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Partially Premixed Combustion (PPC) approaches were applied in a single cylinder diesel research engine in order to characterize engine power improvements. PPC (dual fuel) and PPC (single fuel) are alternative advanced combustion approaches that generally result in lower engine-out soot and NOx emissions, with a moderate penalty in engine-out unburned hydrocarbon (UHC) and carbon monoxide (CO) emissions. In this study, PPC was accomplished with a minority fraction of fuel (isobutanol, iso-octane and jet JP-5) injected into the intake manifold, while the majority fraction of jet JP-5 fuel was delivered directly to the combustion chamber near the start of combustion (SOC). Four compression ratios (CR) were studied. Exhaust emissions plus exhaust opacity and particulate measurements were performed during the experiments in addition to fast in-cylinder combustion metrics.

Primary diesel and gasoline reference fuels, along with secondary reference diesel fuels across a very broad cetane range were tested in an Ignition Quality Tester (IQT) unit using the ASTM D6890 protocol. Additionally, numerous pure component fuels across a range of hydrocarbon size and structure were evaluated. The reference fuels’ ignition delay (IGD) followed expected trends, however, the diesel PRF fuels in the low cetane range produced DCNs (derived cetane numbers) that were moderately higher (shorter IGDs) than their cetane reference values. From the perspective of fuel size, IGD shows a significant ‘shortening’ - faster nature with increased fuel carbon number. For a given carbon number fuel molecule, normal alkanes showed the ‘fastest’ IGD, with alkenes and branched alkyl aromatics leading to moderately longer IGDs. Cyclo-paraffins had the ‘slowest’ - longest IGDs. Various methods were used to determine the IGD of the various fuels.

The US Navy is in the process of evaluating Catalytic Hydrothermal Conversion Jet fuel (CHCJ-5) for inclusion in the JP-5 specification, MIL-DTL-5624, and evaluating Catalytic Hydrothermal Conversion Diesel fuel (CHCD-76) for inclusion in the F-76 specification, MILDTL-16884. CHC fuels are produced from renewable feedstocks such as triglycerides, plant oils, and fatty acids. A Catalytic Hydrothermolysis process chemically converts these feedstocks into a mixture of paraffins, cycloparaffins, aromatics, olefins, and organic acids. The resulting mixture is then hydroprocessed and fractionated to produce a kerosene (or diesel) product having a distillation profile comparable to traditional petroleum derived fuels. The end product is a fuel that is able to meet the jet (or diesel) chemical and physical MIL-SPEC requirements without blending with conventional petroleum fuels.

A new Alcohol To Jet (ATJ) fuel has been developed using a process which takes biomass feedstock to produce a branched butanol molecule. Further dehydration, reforming and hydro-treating produced principally a highly branched C12 iso-paraffin molecule. This ATJ fuel with a low cetane value (DCN = 18) was blended with Navy jet fuel (JP5) in various quantities and tested in order to determine how much ATJ could be blended before diesel engine operation became problematic (the US Navy and Marine Corps may use jet fuel in their diesel engines). Blends of 20%, 30% and 40% ATJ (by volume) were tested with jet fuel. The Derived Cetane Number (DCN) falls from 45 for the base JP5 to 38 with the 40% ATJ component blended in. Engine start performance was evaluated on two Yanmar engines and a Waukesha CFR diesel engine and showed that engine start times increased steadily with increasing ATJ content.

A new alternative fuel has been tested in a number of engines and compared to conventional Navy diesel fuel performance using in-cylinder based diagnostics and brake performance comparisons. This new fuel is derived from a Direct Sugar to Hydrocarbon (DSH) process in which sugar and yeast produce a farnesene type hydrocarbon molecule (branched hydrocarbon with multiple double bonds) which is then processed into a moderately branched single alkane molecule (> 98% purity) with a moderately higher cetane number than conventional diesel fuels. This new fuel was extensively characterized and has a lower density, viscosity and bulk modulus as compared to conventional diesel fuel. These physical property differences lead to later Start of Injection times in three diesel engines (AM General GEP, Waukesha CFR and Yanmar). However, due to the increased reactivity of DSH, ignition delay is reduced - faster across most of the speeds and loads tested.

Alternative diesel fuels from various renewable sources have recently been achieving high volume production status. These fuels are generally paraffinic in nature, and are notably absent of aromatic and cyclo-paraffinic hydrocarbon compounds. Combustion differences exist with these new fuels. Ignition delay and combustion duration are often different than conventional fuels leading to changes in combustion phasing and thus differences in engine brake metrics. How much of an indicated combustion change is acceptable? Currently no alternative fuel combustion acceptance criteria or metrics exist for new alternative fuels in diesel engines. In this paper a proposed set of indicated combustion acceptance criteria is presented with companion data from two new hydro-treated renewable fuels in a legacy military diesel engine. The three combustion criteria are: 1. relative change in ignition delay, 2. Angle of Peak pressure (AOP location) and 3. relative maximum rate of heat release.