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The increased interest in ammonia as a hydrogen carrier and a carbon-free fuel for combustion applications continues to present several challenges to address. Moreover, the high auto-ignition temperature (925 K) for ammonia limits its use in compression ignition engines because excessively high compression ratio are required. One way to retrofit diesel engine is to help the ignition by injecting a pilot injection of reactive fuel, like diesel or biodiesel. In this study, the ammonia engine ignited by a dodecane pilot injection is investigated with a maximum ammonia energy share (until 98.5%). The effect of split diesel injection strategy in two-steps under medium load operating conditions is studied as a function of ammonia/air equivalence ratio. Splitting this injection reduces NOX, CO, UHC and unburnt NH3 emissions at the exhaust, even it remains above the recommended emissions limit, especially at stoichiometric or slightly rich ammonia/air mixture.

The goal of mitigating climate change has driven research to the use of carbon-free energy sources. In this regards, green hydrogen appears as one of the best options, however, its storage remains difficult and expensive. Indeed, there is room to consider the use of ammonia (an efficient hydrogen carrier) directly as a fuel for internal combustion engines or gas turbines. Currently, there are very few works in the literature describing liquid ammonia sprays, both from experimental and modeling point of view, and especially dealing with flash-boiling conditions. In this research work, the direct injection ammonia spray is modeled with the Lagrangian particle approach, building up a numerical model within the OpenFOAM framework, for transient analyses using the U-RANS approach.

Diesel spray mixture formation is investigated at target conditions using multiple diagnostics and laboratories. High-speed Particle Image Velocimetry (PIV) is used to measure the velocity field inside and outside the jet simultaneously with a new frame straddling synchronization scheme. The PIV measurements are carried out in the Engine Combustion Network Spray A target conditions, enabling direct comparisons with mixture fraction measurements previously performed in the same conditions, and forming a unique database at diesel conditions. A 1D spray model, based upon mass and momentum exchange between axial control volumes and near-Gaussian velocity and mixture fraction profiles is evaluated against the data.

Ammonia is now recognized as a very serious asset in the context of the hydrogen energy economy, thanks to its non-carbon nature, competitive energy density and very mature production, storage and transport processes. If produced from renewable sources, its use as a direct combustion fuel could participate to the flexibility in the power sector as well as help mitigating fossil fuel use in certain sectors, such as long-haul shipping. However, ammonia presents unfavorable combustion properties, requiring further investigation of its combustion characteristics in practical systems. In the present study, a modern single-cylinder spark-ignition engine is fueled with gaseous ammonia/air mixtures at various equivalence ratios and intake pressures. The results are compared with methane/air and previous ammonia/hydrogen/air measurements, where hydrogen is used as combustion promoter. In-cylinder pressure and exhaust concentrations of selected species are measured and analyzed.

While the optimization of the internal combustion engine (ICE) remains a very important topic, alternative fuels are also expected to play a significant role in the reduction of CO2 emissions. High energy densities and handling ease are their main advantages amongst other energy carriers. Ammonia (NH3) additionally contains no carbon and has a worldwide existing transport and storage infrastructure. It could be produced directly from renewable electricity, water and air, and is thus currently considered as a smart energy carrier and combustion fuel. However, ammonia presents a low combustion intensity and the risk of elevated nitrogen-based emissions, thus rendering in-depth investigation of its suitability as an ICE fuel necessary. In the present study, a recent single-cylinder spark-ignition engine is fueled with gaseous ammonia/hydrogen/air mixtures at various hydrogen fractions, equivalence ratios and intake pressures.

Small closely-coupled post injections of fuel in diesel engines are known to reduce engine-out soot emissions, but the relative roles of various underlying in-cylinder mechanisms have not been established. Furthermore, the efficacy of soot reduction is not universal, and depends in unclear ways on operating conditions and injection schedule, among other factors. Consequently, designing engine hardware and operating strategies to fully realize the potential of post-injections is limited by this lack of understanding. Following previous work, several different post-injection schedules are investigated using a single-cylinder 2.34 L heavy-duty optical engine equipped with a Delphi DFI 1.5 light-duty injector. In this configuration, adding a closely-coupled post injection with sufficiently short injection duration can increase the load without increasing soot emissions.

Reactivity Controlled Compression Ignition (RCCI) is an approach to increase engine efficiency and lower engine-out emissions by using in-cylinder stratification of fuels with differing reactivity (i.e., autoignition characteristics) to control combustion phasing. Stratification can be altered by varying the injection timing of the high-reactivity fuel, causing transitions across multiple regimes of combustion. When injection is sufficiently early, combustion approaches a highly-premixed autoignition regime, and when it is sufficiently late it approaches more mixing-controlled, diesel-like conditions. Engine performance, emissions, and control authority over combustion phasing with injection timing are most favorable in between, within the RCCI regime.

The transportation sector adds to the greenhouse gas emissions worldwide. One way to decrease this impact from transportation is by using renewable fuels. Ethanol is a readily available blend component which can be produced from bio blend­stock, currently used blended with gasoline from low to high concentrations. This study focuses on a high octane (RON=97) gasoline blended with 0, 20, and 50, volume % of ethanol, respectively. The high ethanol blended gasoline was used in a light duty engine originally designed for diesel combustion. Due to the high octane rating and high ignition resistance of the fuel it required high intake temperatures of 443 K and higher to achieve stable combustion in in homogeneously charged compression ignition (HCCI) combustion operation at low load. To enable combustion with lower intake temperatures more commonly used in commercial vehicles, ozone was injected with the intake air as an ignition improver.

The present investigation examines a new way to control the homogeneous charge compression ignition (HCCI) process. An ozone generator was set up to seed the intake of a single-cylinder engine with low concentrations of ozone. Two kinds of gas supply were tested: an oxygen supply and an air supply; as well as two kinds of injection: a plenum injection and an injection inside one of the intake pipes. The results showed that air can easily be used and that the second injection mode is the best way to achieve an on-road application. Moreover, experiments demonstrated that each combustion parameter such as the phasing, the indicated mean effective pressure and the pollutants can be controlled by varying the capacity of the ozone generator. Then, from experimental results, two dynamic control approaches on the maximum pressure phasing were proposed.

In this paper, a semi-empiric fuel spray tip penetration model is proposed. It is applied to single and double injection strategies taking into account the early and far field penetration. The model is based on the momentum flux as initially proposed by [1] for single injection but it is derived from mean mass flow rate herein. Fuel spray interaction with entrainment air is taken into account for the second injection. The proposed model is calibrated and validated using data from 9 experiments conducted with an indirect piezoelectric diesel injector under various injection strategies. The experiments included 1) injection rate measurements using the Bosch method to determine mean mass flow rate during injector opening as well as obtaining injection duration which are both entry parameters to the model; 2) Fuel spray tip penetrations were measured in a pressure vessel using high speed photography for single and double injection strategies.

In Spark Ignition engines, the heat release rate is not only piloted by the mixture reactivity but also by its sensitivity to stretch effects. Only few results can be found in the literature about flame stretch effect in SI engine configurations. For this study, three different fuels (Methane, Propane, Iso-octane) were studied, but at different air-fuel lean mixture conditions, to present almost equivalent laminar flame speeds and thermo-dynamical properties at ignition timing condition. Besides those mixtures present different Lewis numbers which are relevant parameters to describe flame-stretch interactions. Mie-scattering tomography was then performed in an optical Spark Ignition (S.I.) engine. Using a high speed camera, flame propagation images were acquired through the piston. Thermodynamic analyses based on in-cylinder pressure traces were performed to estimate in-cylinder temperature and burnt mass fraction during the engine cycle.

In this work, the first injection of gasoline was maintained at 30 CAD Before TDC and the second one was swept between 10 CAD Before TDC to 5 CAD After TDC, in order to demonstrate the ideal positioning of the second injection. The results showed that when it was placed near TDC, low emissions, acceptable noise and acceptable efficiencies could be obtained. The effect of EGR, simulated by N2 addition, was also studied. As expected, globally the effect of the EGR rate was to delay the combustion phasing and to decrease NOx emissions. The optimal EGR dilution rate was found to be 30% with respect to the cycle-to-cycle variation criterion (< 5%). Increasing the dilution rate increased HC, CO and PM emissions, due to a considerable delay in combustion phasing caused by the reduction in the fuel reaction rate and the in-cylinder lack of oxygen when the EGR rate reached 30%. The impact of the fuel mass distribution between the two injections was also considered.

Recent works have demonstrated the possibility of operating compression ignition engine with high resistance to auto-ignition fuels as gasoline. By using gasoline and dilution by exhaust gas recirculation, compression ignition can reach high efficiencies and low particulate (PM) and NOx emissions. One of the promising strategies to reach this combustion is the Gasoline Partially Premixed Combustion (GPPC) concept. First step of the study was to optimize the run of a single cylinder Diesel engine in GPPC with double injections strategy by change the second injection phasing and EGR level. The optimum in terms of heat release rate and regulated pollutant emissions was obtained for second injection timing around TDC and an EGR level at 30%.

Nowadays, the main objectives in the automobile engine field are to reduce fuel consumption and pollutant emissions. HCCI engines can be a good solution to meet pollutant emission requirements and to achieve high combustion efficiency. However, before an HCCI engine is used as a conventional engine, several problems must be overcome, in particular control of the progression of combustion. Many studies have been conducted into possible control methods. A new strategy consists in using oxidizing chemical species such as ozone to seed the intake of a HCCI engine. As increasingly smaller ozonizers are now being designed, this kind of device could be integrated on a vehicle and on a HCCI engine, in order to control combustion phasing and promote the future use of this engine as a conventional engine. In the present study, experiments on a HCCI engine fuelled with iso-octane were carried out with ozone seeding in the intake.

Among the new combustion concepts envisaged to meet future regulations, the Dual Fuel (DF) concept is considered to be an attractive strategy due to its potential to reduce CO2 emissions and engine-out pollutant emissions levels. A small quantity of high-cetane fuel (Diesel) is injected in the combustion chamber in order to ignite a homogeneous mixture of air and a highly volatile fuel (gasoline in our study). The DF concept has been shown to achieve improved engine thermal efficiency and low engine-out NOx and soot emissions. However, the physical mechanisms controlling DF combustion and in particular, determination of the predominant combustion regime(s) are not yet well understood. In this study, numerical simulations (CFD) and optical engine measurements are used to investigate Dual Fuel combustion.

As an alternative to second generation ethanol, valeric esters can be produced from lignocellulose through levulinic acid. While some data on these fuels are available, only few experiments have been performed to analyze their combustion characteristics under engine conditions. Using a traditional spark ignition engine converted to mono-cylinder operation, we have investigated the engine performances and emissions of methyl and ethyl valerates. This paper compares the experimental results for pure valeric esters and for blends of 20% of esters in PRF95, with PRF95 as the reference fuel. The esters propagate faster than PRF95 which requires a slight change of ignition timing to optimise the work output. However, both the performances and the emissions are not significantly changed compared to the reference. Accordingly, methyl and ethyl valerate represent very good alternatives as biofuels for SI engines.

The current decrease in fossil energy resources requires a diversification of the liquid and gaseous fuels potentially consumable in internal combustion engines. The use of these fuels modifies the combustion process and the heat released as well. In a Spark Ignition (SI) engine, the heat released is mainly piloted not only by the mixture reactivity but also by its sensitivity to stretch effects. Only a few results can be found in the literature about stretch effects for SI engine configurations. The purpose of the present paper is to evaluate stretch effects on the flame front propagation in an optical SI engine and to investigate the relative importance of these effects depending on the fuel considered. Different air-fuel mixtures presenting different flame stretch sensitivities were selected. Four different engine regimes (1400, 1600, 1800 and 2000 rpm) were studied for all the mixtures in order to evaluate the impact of different turbulence intensities.

In the present study, experiments were carried out in a single-cylinder downsized SI engine with different rates of oxygen (15% to 27% by volume in the total mixture of intake gases except fuel) and equivalence ratios (from 0.45 to 1). Therefore, the oxygen volume fraction is due to oxygen enrichment or nitrogen dilution. The study of the impact of controlling oxygen concentration on the combustion characteristics and emissions was performed at 1400 rpm, at several loads (Indicated Mean Effective Pressure (IMEP) from 400 to 1000 kPa). For each operation point, the spark advance and the intake pressure were adjusted simultaneously in order to maintain the load and obtain a minimum value of indicated Specific Fuel Consumption (SFC). The effect of oxygen concentration on the engine combustion characteristics was simulated by using the commercial software AMESim, with the combustion model developed by IFP-EN, and an adapted algorithm was used to avoid residual gas calibration.