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Within the Cluster of Excellence “Tailor-Made Fuels from Biomass” (TMFB) at the RWTH Aachen University, two novel biogenic fuels, namely 1-octanol and its isomer dibutyl ether (DBE), were identified and extensively analyzed in respect of their suitability for combustion in a Diesel engine. Both biofuels feature very different properties, especially regarding their ignitability. In previous works of the research cluster, promising synthesis routes with excellent yields for both fuels were found, using lignocellulosic biomass as source material. Both fuels were investigated as pure components in optical and thermodynamic single cylinder engines (SCE). For 1-octanol at lower part load, almost no soot emission could be measured, while with DBE the soot emissions were only about a quarter of that with conventional Diesel fuel. At high part load (2400 min-1, 14.8 bar IMEP), the soot reduction of 1-octanol was more than 50% and for DBE more than 80 % respectively.

This work is a continuation of earlier results presented by the authors. In the current investigations the biofuels hydrogenated vegetable oil (HVO) and 1-octanol are investigated as pure components and compared to EN 590 Diesel. In a final step both biofuels are blended together in an appropriate ratio to tailor the fuels properties in order to obtain an optimal fuel for a clean combustion. The results of pure HVO indicate a significant reduction in CO-, HC- and combustion noise emissions at constant NOX levels. With regard to soot emissions, at higher part loads, the aromatic free, paraffinic composition of HVO showed a significant reduction compared to EN 590 petroleum Diesel fuel. But at lower loads the high cetane number leads to shorter ignition delays and therefore, ignition under richer conditions.

Within this study a dual-fuel concept was experimentally investigated. The utilized fuels were conventional EN228 RON95E10 and EN590 Diesel B7 pump fuels. The engine was a single cylinder Diesel research engine for passenger car application. Except for the installation of the port fuel injection valve, the engine was not modified. The investigated engine load range covered low part load operation of IMEP = 4.3 bar up to IMEP = 14.8 bar at different engine speeds. Investigations with Diesel pilot injection showed that the dual-fuel approach can significantly reduce the soot/NOx-trade-off, but typically increases the HC- and CO-emissions. At high engine load and gasoline mass fraction, the premixed gasoline/air self-ignited before Diesel fuel was injected. Reactivity Controlled Compression Ignition (RCCI) was subsequently investigated in a medium load point at IMEP = 6.8 bar.

A new index to evaluate the inherent soot reduction in a diesel-like spray plume is proposed in this study. The index is named “Oxidation Potential Number” and was derived with the help of a computational fluid dynamics (CFD) software. C8 - C16 n-alkanes, 1-alcohols and di-n-ethers were studied with the help of this index over four part load engine operating conditions, representative of a C-class diesel vehicle. The CFD modelling results have shown that C8 molecules feature a higher potentiality to reduce the soot. Thus, C8 molecules were tested in a single cylinder diesel engine over the same operating conditions. In conclusion, the proposed index is compared with the soot engine out emission.

This study investigated dual-fuel operation with a light duty Diesel engine over a wide engine load range. Ethanol was hereby injected into the intake duct, while Diesel was injected directly into the cylinder. At low loads, high ethanol shares are critical in terms of combustion stability and emissions of unburnt hydrocarbons. As the load increases, the rates of heat release become problematic with regard to noise and mechanical stress. At higher loads, an advanced injection of Diesel was found to be beneficial in terms of combustion noise and emissions. For all tests, engine-out NOx emissions were kept within the EU-6.1 limit.

With increasing interest in new biofuel candidates, 1-octanol and di-n-butylether (DNBE) were presented in recent studies. Although these molecular species are isomers, their properties are substantially different. In contrast to DNBE, 1-octanol is almost a gasoline-type fuel in terms of its auto-ignition quality. Thus, there are problems associated with engine start-up for neat 1-octanol. In order to find a suitable glow-plug position, mixture formation is studied in the cylinder under almost idle operating conditions in the present work. This is conducted by planar laser-induced fluorescence in a high-speed direct-injection optical diesel engine. The investigated C8-oxygenates are also significantly different in terms of their evaporation characteristics. Thus, in-cylinder mixture formation of these two species is compared in this work, allowing conclusions on combustion behavior and exhaust emissions.

Lignocellulosic biomass consists of (hemi-) cellulose and lignin. Accordingly, an integrated biorefinery will seek to valorize both streams into higher value fuels and chemicals. To this end, this study evaluated the overall combustion performance of both cellulose- and lignin derivatives, namely the high cetane number (CN) di-n-butyl ether (DnBE) and low CN anisole, respectively. Said compounds were blended both separately and together with EN590 diesel. Experiments were conducted in a single cylinder compression ignition engine, which has been optimized for improved combustion characteristics with respect to low emission levels and at the same time high fuel efficiency. The selected operating conditions have been adopted from previous “Tailor-Made Fuels from Biomass (TMFB)” work.

Within this paper, the two possible alternative and biomass-based fuel candidates Di-n-butyl ether (DNBE) and 1-octanol are investigated with regard to their utilization in a diesel-type engine. In order to asses the fuels emission-reduction potential, both have been tested in a single cylinder engine (SCE) and a high pressure chamber (HPC) in comparison to conventional EN590 diesel at various load points. Due to its reduced reactivity 1-octanol features a longer ignition delay and thus higher degrees of homogenization at start of combustion, whereas DNBE ignites rather rapidly in both the HPC and the engine leading to a predominantly mixing controlled combustion. Thus, both fuels feature completely different combustion characteristics. However, compared to diesel, both fuels contribute to a significant reduction in Filter Smoke Number (FSN) up to a factor of 15.

The residue and waste streams of existing industry offer feasible and sustainable raw materials for biofuel production. All kind of biomass contains carbon and hydrogen which can be turned into liquid form with suitable processes. Using hydrotreatment or Biomass-to-Liquid technologies (BTL) the liquid oil can be further converted into transportation biofuels. Hydrotreatment technology can be used to convert bio-oils and fats in to high quality diesel fuels that have superior fuel properties (e.g. low aromatic content and high cetane number) compared to regular diesel fuel and first generation ester-type diesel fuel. UPM has developed a new innovative technology based on hydrotreatment that can be used to convert Crude Tall Oil (CTO) into high quality renewable diesel fuel. This study concentrated on determining the functionality and possible effects of CTO based renewable diesel as a blending component on engine emissions and engine performance.

Modern biofuels offer the potential to decrease engine out emissions while at the same time contributing to a reduction of greenhouse gases produced from individual mobility. In order to deeply investigate and improve the complete path from biofuel production to combustion, in 2007 the cluster of excellence “Tailor-Made Fuels from Biomass” was installed at RWTH Aachen University. Since then, a whole variety of possible fuel candidates have been identified and investigated. In particular oxygenated fuels (e.g. alcohols, furans) have proven to be beneficial regarding the particulate matter (PM)/ NOx trade-off [1, 2, 3] in diesel-type combustion. Alcohols that provide a longer ignition delay than diesel might behave even better with regard to this trade-off due to higher homogenization of the mixture. Recent studies carried out within the Cluster of Excellence have discovered new pathways to derive 1-octanol from biomass [4], which features a derived cetane number (DCN) of 39.

In order to thoroughly investigate and improve the path from biofuel production to combustion, the Cluster of Excellence “Tailor-Made Fuels from Biomass” was installed at RWTH Aachen University in 2007. Since then, a variety of fuel candidates have been investigated. In particular, 2-methyl tetrahydrofurane (2-MTHF) has shown excellent performance w.r.t. the particulate (PM) / NOx trade-off [1]. Unfortunately, the long ignition delay results in increased HC-, CO- and noise emissions. To overcome this problem, the addition of di-n-butylether (DNBE, CN ∼ 100) to 2-MTHF was analyzed. By blending these two in different volumetric shares, the effects of the different mixture formation and combustion characteristics, especially on the HC-, CO- and noise emissions, have been carefully analyzed. In addition, the overall emission performance has been compared to EN590 diesel.

Demand for transport energy is growing but this growth is skewed heavily toward commercial transport, such as, heavy road, aviation, marine and rail which uses heavier fuels like diesel and kerosene. This is likely to lead to an abundance and easy availability of lighter fractions like naphtha, which is the product of the initial distillation of crude oil. Naphtha will also require lower energy to produce and hence will have a lower CO₂ impact compared to diesel or gasoline. It would be desirable to develop engine combustion systems that could run on naphtha. Many recent studies have shown that running compression ignition engines on very low Cetane fuels, which are very similar to naphtha in their auto-ignition behavior, offers the prospect of developing very efficient, clean, simple and cheap engine combustion systems. Significant development work would be required before such systems could power practical vehicles.

Future vehicles will increasingly be required to improve their efficiency, reduce both regulated and CO₂ emissions, and maintain acceptable levels of driving, safety, and noise performance. To achieve this high level of performance, they will be configured with more advanced hardware, sensors, and control technologies that will also enable their operation on a broader range of fuel properties. These capabilities offer the potential to design future vehicles to operate on the most widely available and GHG-reducing fuels. In previous studies, fuel flexibility has been demonstrated on a compression ignition bench engine and vehicle equipped with an advanced engine management system, closed-loop combustion control, and air-path control strategies. An unresolved question is whether engines of this sort can operate routinely on market gasoline while achieving diesel-like efficiency and acceptable emissions and noise levels.