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High frequency ignition (HFI) and conventional transistor coil ignition (TCI) were investigated with an optically accessible single-cylinder research engine to gain fundamental understanding of the chemical reactions taking place prior to the onset of combustion. Instead of generating heat in the gap of a conventional spark plug, a high frequency / high voltage electric field is employed in HFI to form chemical radicals. It is generated using a resonant circuit and sharp metallic tips placed in the combustion chamber. The setup is optimized to cause a so-called corona discharge in which highly energized channels (streamers) are created while avoiding a spark discharge. At a certain energy the number of ionized hydrocarbon molecules becomes sufficient to initiate self-sustained combustion. HFI enables engine operation with highly diluted (by air or EGR) gasoline-air mixtures or at high boost levels due to the lower voltage required.