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Technical Paper

About Cross-Sensitivities of NOx Sensors in SCR Operation

2013-04-08
2013-01-1512
Meeting the upcoming NOx emissions standards is a major challenge for the lean-burn engines, thus requiring a highly efficient exhaust gas aftertreatment. Currently, the Selective Catalytic Reduction (SCR) appears to be the most promising technology, especially when operated with two kinds of reductants: ammonia (generally derived from urea) and ethanol. In order to reach high conversion levels while avoiding the overinjection of the reductant, a very accurate model-based control assisted with at least one NOx sensor is required. This study focuses on the sensitivity of NOx sensors to the main nitrogenous species encountered: ammonia, isocyanic acid (HNCO) and hydrogen cyanide (HCN). The cross-sensitivity to ammonia is the only one to be already described in literature and already used in the urea-SCR control systems to limit the risks of ammonia-slip. However, HNCO can also be found downstream of a catalyst during urea-SCR if the urea delivery or the catalyst are deficient.
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