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Biodiesel is considered one of the most promising alternative fuels to petrol fuels. In this study, an attempt has been made to investigate and compare the effect of fuel injection pressure, injection timing, and exhaust gas recirculation (EGR) ratio on the particle size distributions and exhaust emissions of the diesel and biodiesel produced from waste cooking oil (WCO) used in a common rail direct injection (CRDI) diesel engine. The engine tests were conducted at two injection pressures (800 and 1600 bar), two injection timings (25 and 5 deg before top dead center (bTDC) and three EGR ratios (10%, 20% 30%) at a constant fuel injection energy per stroke and engine speed (1200 r/min). The results indicated that carbon monoxide (CO) and hydrocarbon (HC) emissions of biodiesel were slightly lower, but nitrogen oxide (NOx) emissions were slightly higher, than those of diesel fuel under most operating conditions.

The characteristics of soot particles in an exhaust gas for low temperature diesel combustion (LTC) compared with conventional combustion in a compression ignition engine were experimentally investigated by the elemental and thermogravimetric analysis (TGA). Morphology of soot particles was also studied by the transmission electron microscopy (TEM). From the result of the TGA, the water can be evaporated until about 150°C for both combustion regimes. The soot particles for LTC contained more volatile hydrocarbons, which can be easily evaporated from 200°C to 420°C compared with conventional diesel combustion. The soot oxidation for conventional combustion occurs up to 600°C, on the other hand the particles for LTC is oxidized below 520°C. Elemental analysis showed higher oxygen weight fraction resulted from the oxygenated hydrocarbon for the soot particles in LTC. TEM has shown primary particles to be in a diameter range of 20 to 50 nm for conventional diesel combustion.

An experimental study was conducted to investigate the impact of injection parameters on the combustion and emission characteristics in a compression ignition engine fuelled with neat waste cooking oil (WCO) biodiesel. A single-cylinder diesel engine equipped with common-rail system was used in this research. The test was performed over two engine loads at an engine speed of 800 r/min. Injection timing was varied from −25 to 0 crank angle degree (CAD) after top dead center (aTDC) at two different injection pressures (80 and 160 MPa). Based on in-cylinder pressure, heat release rate was calculated to analyze the combustion characteristics. Carbon monoxide (CO), hydrocarbon (HC), nitrogen oxide (NOx) and smoke were measured to examine the emission characteristics. The results showed that the indicated specific fuel consumption (ISFC) of WCO biodiesel was higher than that of diesel. The ISFC was increased as the injection timing was advanced and injection pressure was increased.