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As lithium-ion cells and systems become larger and more ubiquitous in automotive applications, fire and explosion hazards that are rare or non-existent in smaller systems may exist in these larger systems. One potential hazard can occur when flammable gases emitted from a lithium-ion cell failure accumulate in or around automobiles and are ignited by electrical activity or by the cells themselves and result in a fire or explosion. In some instances, the safety aspects related to fires and explosions protection of electric vehicles and hybrid vehicles using these large energy storage battery packs are a significant challenge to address. This paper describes and characterizes the combustion and explosion hazards that can occur when a lithium ion battery pack fails and goes into thermal runaway in an enclosed space. Metrics such as gas composition, maximum overpressure, rate of pressure rise, and flammability limits are described.