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The blend of dimethyl ether (DME, CH3OCH3) and propane (C3H8) is a potentially renewable fuel mixture that has the potential to replace diesel in compression ignition engines. The combination can potentially reduce particulate and greenhouse gas emissions compared to a conventional diesel engine operating under similar conditions. However, detailed conceptual and simulation studies must be conducted before adopting a new fuel on a compression ignition engine. For these simulations, accurate chemical kinetic models are necessary. However, the validity of chemical kinetic mechanisms in the literature is unknown for mixing controlled compression ignition (MCCI) engine operating conditions. Hence, in this work, we studied the ignition of dimethyl ether (DME) and propane blends in a shock tube at MCCI engine conditions. Ignition delay time (IDT) data was collected behind the reflected shock for DME-propane mixtures for heavy-duty compression ignition (CI) engine parameters.

An experimental study on the laminar flame speeds (LFS) of premixed propane/dimethyl-ether (DME)/air flames was conducted inside a constant-volume chamber at UCF. Mixtures of propane and DME were selected for this study as they show promise as a fuel source that can be utilized in the automotive diesel industry as a low emission alternative fuel. The LFS of a fuel mixture is a crucial characteristic of combustion for its application in the design process of engines, as it can be used as a metric for fuel performance. Further underscoring the importance of gathering LFS data for these mixtures is its use in validating chemical kinetic mechanisms that can be utilized for further research in the field. LFS is dependent on fuel/oxidant mixture temperature, pressure, and equivalence ratio. While some studies exist examining other characteristics of combustion regarding propane/DME fuel mixtures, there is minimal information on the laminar flame speed of the mixtures.

Co-Optimization of Fuels and Engines initiative (Co-Optima) of the U.S Department of Energy started investigations on several candidates of biofuels and blends for internal combustion engines. At this stage, only a few biomass-derived fuel blendstocks (including ethanol) for advanced spark-ignition engines have been selected using enhanced screening criteria, which included boiling point, toxicity, research octane number, octane sensitivity, and economical distribution system, etc. Ethanol, of which this paper is focused on, is also an important fuel because of its high-octane number which in turn promotes advance ignition timing and higher thermal efficiencies in reciprocating engines. Measurements of laminar burning velocity (LBV) is a key metric to understand fuel performance and applicability in engines. Furthermore, in order to quantify more complicated, and practical, burning regimes such as turbulent combustion much of the underlying theory requires knowledge of LBV.

Laminar burning velocity (LBV) measurements are reported for promising high-performance fuels selected as drop-in transportation fuels to automotive grade gasoline as part of the United States Department of Energy’s Co-Optimization of Fuels and Engines Initiative (Co-Optima). LBV measurements were conducted for ethanol, methyl acetate, and 2-methylfuran with synthetic air (79.0 % N2 and 21.0 % O2 by volume) within a constant-volume spherical combustion rig. Mixture initial temperature was fixed at 428±4 K, with the corresponding initial pressure of 1.00±0.02 atm. Current LBV of ethanol is in good agreement with literature data. LBV of ethanol and 2-methylfuran showed similar values over the range of equivalence ratios, while methyl acetate exhibited an LBV significantly lower over the range of tested equivalence ratios. The maximum laminar burning velocity occurred at slightly richer equivalence ratio from the stoichiometric value for all fuels tested.

The 2,4-dimethyl-3-pentanone (DIPK) is a promising biofuel candidate for automotive applications that is produced by the endophytic fungal conversion process which can be optimized for widespread utilization. There are some studies in the literature on combustion properties of DIPK, such as ignition delay times and laminar burning velocity (LBV) measurements. However, most studies are conducted one atmospheric (atm) pressure which are far away from the high-pressure conditions present inside reciprocating engines. Therefore, we present LBV measurements at high pressures up to 10 atm for this fuel using a spherical flame speed facility. It is known that the flame in a constant volume chamber develops cellular structure (hydrodynamic instability) as the initial pressure increases because of the reduction in flame thickness. In addition, the diffusional-thermal instability prevents experiments for rich mixtures because of the reduction of Lewis number (Le).

The biofuel and engine co-development framework was initiated at Sandia National Labs. Here, the synthetic biologists develop and engineer a new platform for drop-in fuel production from lignocellulosic biomass, using several endophytic fungi. Hence this process has the potential advantage that expensive pretreatment and fuel refining stages can be optimized thereby allowing scalability and cost reduction; two major considerations for widespread biofuel utilization. Large concentrations of ketones along with other volatile organic compounds were produced by fungi grown over switchgrass media. The combustion and emission properties of these new large ketones are poorly known.