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To reach close to zero tailpipe NOx emissions, a double-SCR (selective catalytic reduction) system is proposed. In that, the first SCR unit would be placed upstream of the diesel particulate filter (DPF) and the second SCR unit downstream of DPF. This study focused on the experiments of the first SCR unit. The experiments were conducted utilizing a new, 4.4-liter heavy duty diesel engine that was connected to a research facility for studying after-treatment systems in controlled environment. Three different SCR’s: a vanadium-based SCR (V-SCR), a copper-based SCR (Cu-SCR) and a vanadium-based SCR including an ammonia slip catalyst (V-SCR+ASC) were studied. Studies were done at different exhaust temperatures from 215°C to 350°C. Emissions of NO, NO2, NH3, N2O, CO, CO2 and hydrocarbons were measured by FTIR. Particulate emissions (PM, PN) were studied as a part of the experiments. The results showed that the three SCR units performed differently.

In this study the exhaust gas ammonia (NH3) concentrations from different exhaust sources were measured with an ammonia sensor. The aim of the study was to verify whether an NH3 sensor has the potential to be used for monitoring and control purposes for SCR systems. Measurements were performed in laboratory and field conditions and comparison was made between Fourier Transform Infrared (FTIR) and Laser Diode Spectrometer (LDS) measurement techniques. With heavy-duty vehicles, a comparison between an LDS, FTIR and NH3 sensor was performed on a heavy-duty chassis dynamometer. Measurements were performed at steady speeds using a World Harmonized Vehicle Cycle (WHVC) and Braunschweig test cycles. The urea injection rate for the SCR system was varied to generate different ammonia levels in the exhaust gas. NH3 measurements with FTIR and NH3 sensor were performed on large cruise ships using heavy fuel oil (HFO) and marine gas oil (MGO) as fuels.

A new tool for SCR (selective catalytic reduction) testing is developed. This side stream test bench has an advantage to test smaller catalysts with a proper exhaust. The exhaust mass flow and temperature are adjustable. A control program is developed to adjust and save the needed parameters. NOx sensors are utilized in the test bench to measure the levels upstream and downstream of SCR reactor. In this study one SCR with a volume of 40.5 dm3 is tested with exhaust flows ranging from 400 to 600 kg/h and exhaust temperatures from 280 to 360°C. The tests are conducted using exhaust gas from a medium-speed diesel engine running on heavy fuel oil. A decrease from 75% to 99% (depending on test conditions) was observed in NOx over the catalyst. In addition HC and PM were found to decrease while CO was increased over the catalyst. The controlling of exhaust flow and temperature with the test bench succeeded with only minor errors.