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It is known that lean combustion is effective as one of the ways which improves thermal efficiency of a gasoline engine. In the interest of furthering efficiency, the use of leaner mixtures is desired. However, to realize robust lean combustion it is necessary to reduce combustion cyclic variation while managing the emission nitrogen oxides. In this study, combustion analysis was carried out focusing on cyclic variations of the heat release of lean combustion. Since the initial flame kernel growth speed has a great effect on the indicated mean effective pressure, laminar flame speed (LFS) around the spark plug was analyzed. Infrared absorption spectrophotometry was used for the measurement of a fuel concentration around the spark plug. Moreover, a LFS predicting formula, which can be used in an area leaner than before, was drawn from detailed chemical reaction calculation results, and the LFS around the spark plug was also calculated through the use of this formula.

The ignition characteristics of each component of natural gas and the chemical kinetic factors determining those characteristics were investigated using detailed chemical kinetic calculations. Ethane (C2H6) showed a relatively short ignition delay time with high initial temperature; the heat release profile was slow in the early stage of the ignition process and rapid during the late stage. Furthermore, the ignition delay time of C2H6 showed very low dependence on O2 concentration. In the ignition process of C2H6, HO2 is generated effectively by several reaction paths, and H2O2 is generated from HO2 and accumulated with a higher concentration, which promotes the OH formation rate of H2O2 (+ M) = OH + OH (+ M). The ignition characteristics for C2H6 can be explained by H2O2 decomposition governing OH formation at any initial temperature.

The interaction between spark discharge and low-temperature oxidation (LTO) was investigated using an optical compression and expansion machine fueled with n-C7H16 or i-C8H18 for an equivalence ratio of 0.33. Charge pressure was adjusted so that the compression stoke could induce LTO for n-C7H16, but could not lead to high-temperature reactions. A spark was discharged in the field before, during, or after the LTO for n-C7H16 or in the field without LTO for i-C8H18. Reaction zones were induced in the field after the LTO, whereas no reaction zones were induced in the fields before the LTO and without LTO. Local ignitions were induced in the areas surrounding the propagating reaction zones. The reaction zone propagation with the low equivalence ratio must be a different phenomenon from conventional flame propagation. The reaction zones can compress or heat the surrounding areas containing H2O2 and CH2O, and accelerate an H2O2 regeneration loop in the pre-reaction zones.

Engines using natural gas as their main fuel are attracting attention for their environmental protection and energy-saving potential. There is demand for improvement in the thermal efficiency of engines as an energy-saving measure, and research in this area is being actively pursued on spark ignition engines and HCCI engines. In spark ignition gas engines, improving combustion under lean condition and EGR (exhaust gas recirculation) condition is an issue, and many large gas engines use a pre-chamber. The use of the pre-chamber approach allows stable combustion of lean gas mixtures at high charging pressure, and the reduction of NOx emissions. In small gas engines, engine structure prevents the installation of pre-chambers with adequate volume, and it is therefore unlikely that the full benefits of the pre-chamber approach will be derived.

The ignition delay times and heat release profiles of CH4, C2H6, C3H8, i-C4H10, and n-C4H10 and dual-component CH4-based blends with these alkanes in air were determined using a detailed chemical kinetic model. The apparent activation energy of C2H6 in the relationship between initial temperature and ignition delay time is higher than those of the other alkanes because OH formation is dominated by H2O2(+M)=OH+OH(+M) from the beginning over a wide range of initial temperatures. The heat release rate of C2H6 is higher than those of the other alkanes in the late stage of ignition delay time because H2O2 is accumulated with a higher concentration and promotes the OH formation rate of H2O2(+M)=OH+OH(+M). These ignition characteristics are reflected in those of CH4/C2H6.

In practical lean burn engines used to date, the use of a stratified air-fuel configuration, with a comparatively rich mixture in the vicinity of the spark plugs, has resulted in the stable combustion of an overall lean mixture. However, because a comparatively rich mixture is burned during the first half of combustion, NOx emissions are not reduced sufficiently. This research focused on a form of lean burn with homogeneous premixture that would be able to balance low NOx emissions with combustion controllability. It is widely known that homogeneous lean premixed gas has poor flame propagation characteristics. To determine the dominant cause of this, this study investigated the combustion properties of a single-cylinder engine while changing the compression ratio and intake temperature. As a result, the primary cause of combustion fluctuation, the abnormal cycle has a low TDC temperature compared to that of other cycles.

Some experimental data indicate that an HCCI process of a highly diluted mixture is characterized with a two-stage profile of heat release after the heat release by low-temperature oxidation, and with slow CO oxidation into CO₂ at a low temperature. In the present paper, these characteristics are discussed using a detailed chemical kinetic model of normal heptane, and based on an authors' idea that an ignition process can be divided into five phases. The H₂O₂ loop reactions mainly contribute to heat release in a low-temperature region of the TI (thermal ignition) preparation phase. However, H+O₂+M=HO₂+M becomes the main contributor to heat release in a high-temperature region of the TI preparation phase. H₂O₂ is accumulated during the LTO (low-temperature oxidation) and NTC (negative temperature oxidation) phases, and drives the H₂O₂ loop reactions to increase the temperature during the TI preparation phase.

Ignition process chemistry was analyzed using a detailed chemical kinetic model of n-heptane generated by KUCRS (Knowledge-basing Utilities for Complex Reaction Systems), wherein pressure-dependent rate constants of the O₂ addition to alkyl radicals and hydroperoxy alkyl radicals and the thermal decomposition of ketohydroperoxides have been introduced. Then, the effect of the initial pressure and the individual effects of the initial fuel, O₂ and N₂ molar concentrations on a relationship between the initial temperature and the ignition delay were discussed. When the initial temperature increases, the branch of C₇H₁₄OOH removal into the second O₂ addition and the decomposition into C₇H₁₄cyO and OH is more sensitive to the pressure and the O₂ concentration, and thus, the LTO preparation phase is more affected by the pressure and the O₂ concentration. The LTO phase terminates mainly by the OH removal by intermediate species.