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Diesel engines have better fuel economy over comparable gasoline engines and are useful for the reduction of CO2 emissions. However, to meet stringent emission standards, the technology for reducing NOx and particulate matter (PM) in diesel engine exhaust needs to be improved. A conventional selective catalytic reduction (SCR) system consists of a diesel oxidation catalyst (DOC), diesel particulate filter (DPF), and urea-SCR catalyst. Recently, more stringent regulations have led to the development of SCR systems with a larger volume and increased the cost of such systems. In order to solve these problems, an SCR catalyst-coated DPF (SCR/DPF) is proposed. An SCR/DPF system has lower volume and cost compared to the conventional SCR system. The SCR/DPF catalyst has two functions: combustion of PM and reduction of NOx emissions.

Diesel engines provide a solution for the reduction of carbon dioxide (CO2) from motor vehicles. For diesel engines, however, technology to reduce nitrogen oxide (NOx) emissions is essential. This report focuses on Urea - Selective Catalytic Reduction (SCR) as an aftertreatment system for NOx reduction. The NOx conversion performance of SCR catalyst depends on exhaust gas temperature and the NO2/NOX ratio. In order to raise the NO2/NOX ratio, it is essential to raise the temperature of oxidation catalyst. For these purposes, it is necessary to raise the temperature of oxidation catalyst and SCR catalyst to high level in order to enhance NOx conversion. Temperature rising is implemented by in-cylinder fuel injection (post-injection).

A diesel engine is possible solution for carbon dioxide (CO2) reduction from automobiles. However, it is necessary for a diesel engine vehicle to reduce nitrogen oxide (NOx) emission. Therefore, this research focused on a Urea-selective catalytic reduction (urea-SCR) system as an after-treatment system to convert NOx and proposes the control method of the urea-SCR system based on the output of an ammonia (NH3) sensor. By maximizing NH3 storage rate of the SCR, conversion performance is maximized. To maximize the NH3 storage rate, an NH3 sensor is installed downstream of the SCR. The amount of urea-solution is controlled to keep NH3 slip detected by the sensor. Thus, the NH3 storage amount in the SCR or the SCRF (SCR on filter) can be maximized. The estimation and the control of NH3 storage amount is also used to cause NH3 slip immediately. NH3 storage capacity changes with catalyst temperature. In a transient state, temperature distribution occurs in the SCR catalyst.

Manganese oxides show high catalytic activity for CO and HC oxidation without including platinum group metals (PGM). However, there are issues with both thermal stability and resistance to sulfur poisoning. We have studied perovskite-type YMnO₃ (YMO) with the aim of simultaneously achieving both activity and durability. This paper describes the oxidation activity of PGM-free Ag/i-YMO, which is silver supported on improved-YMO (i-YMO). The Ag/i-YMO was obtained by the following two methods. First, Mn⁴+ ratio and specific surface area of YMO were increased by optimizing composition and preparation method. Second, the optimum amount of silver was supported on i-YMO. In model gas tests and engine bench tests, the Ag/i-YMO catalyst showed the same level of activity as that of the conventional Pt/γ-Al₂O₃ (Pt = 3.0 g/L). In addition, there was no degradation with respect to either heat treatment (700°C, 90 h, air) or sulfur treatment (600°C to 200°C, total 60 h, 30 ppm SO₂).