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All previous correlations of the ignition delay (ID) period in diesel combustion show a positive activation energy, which means that shorter ID periods are achieved at higher charge temperatures. This is not the case in the autoignition of most homogeneous hydrocarbons-air mixtures where they experience the NTC (Negative Temperature Coefficient ) regime in the intermediate temperature range, from about 800 K to 1000 K). Here, the autoignition reactions slow down and longer ID periods are experienced at higher temperatures. Accordingly the global activation energy for the autoignition reactions of homogeneous mixtures should vary from positive to negative values.

This paper presents the results of an experimental investigation on a single cylinder engine to validate a two-component JP-8 surrogate. The two-component surrogate was chosen based on a previous investigation where the key properties, such as DCN, volatility, density, and lower heating value, of the surrogate were matched with those of the target JP-8. The matching of the auto-ignition, combustion, and emission characteristics of the surrogate with JP-8 was investigated in an actual diesel engine environment. The engine tests for the validation of the surrogate were conducted at an engine speed of 1500 rpm, a load of 3 bar, and different injection timings. The results for the cylinder gas pressure, ignition delay period, rate of heat release, and the CO, HC, and NOx emissions showed a good match between the surrogate and the target JP-8. However, the engine-out particulate matter for the surrogate was lower than that for the JP-8 at all tested conditions.

This paper investigates the effect of boost pressure and intake temperature on the auto-ignition of fuels with a wide range of properties. The fuels used in this investigation are ULSD (CN 45), FT-SPK (CN 61) and two blends of JP-8 (with CN 25 and 49). Detailed analysis of in-cylinder pressure and rate of heat release traces are made to correlate the effect of intake pressure and injection strategy on the events immediately following start of injection leading to combustion. A CFD model is applied to track the effect of intake pressure and injection strategy on the formation of different chemical species and study their role and contribution in the auto-ignition reactions. Results from a previous investigation on the effect of intake temperature on auto-ignition of these fuels are compared with the results of this investigation.