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SASOL IPK is a low cetane number synthetic fuel formed from coal by the Fischer-Tropsch process which can be used as an extender to JP8, currently used in military ground vehicles. This paper presents two surrogates developed considering the following criteria: (a) availability of kinetic combustion models for each component, (b) smallest number of components to reduce computation time and cost, (c) matching the following properties of target fuel DCN, distillation curve, density, LHV, MW and H/C ratio. The autoignition and combustion characteristics of the surrogates were validated in IQT according to ASTM D6890-10a. Surrogate formulation strategy involves an equation to calculate DCN of the surrogate mixture from the DCN of each component. The linear equation commonly used for such calculations was modified to include a multiplier, based on regression analysis, for each component to produces DCN values that agree well with the measured DCN in the IQT.

All previous correlations of the ignition delay (ID) period in diesel combustion show a positive activation energy, which means that shorter ID periods are achieved at higher charge temperatures. This is not the case in the autoignition of most homogeneous hydrocarbons-air mixtures where they experience the NTC (Negative Temperature Coefficient ) regime in the intermediate temperature range, from about 800 K to 1000 K). Here, the autoignition reactions slow down and longer ID periods are experienced at higher temperatures. Accordingly the global activation energy for the autoignition reactions of homogeneous mixtures should vary from positive to negative values.

This paper presents a new approach for the development of six different JP-8 surrogates for application in diesel cycle simulation. The approach involves a step-wise formulation of 2-, 3-, and 4-component surrogates from a list of pure compounds which are selected based on several criteria. A MATLAB code is developed and is used in conjunction with the Ignition Quality Tester (IQT) and HYSYS software in order to formulate optimal surrogates. The first part of the results shows a comparison between the calculated and the measured DCNs for six surrogates. The differences in the properties such as the density, volatility, lower heating value, H/C ratio, molecular weight, and threshold sooting index of the surrogates and the JP-8 are also highlighted. This is followed by the evaluation of the surrogates with respect to the target JP-8 fuel. The evaluation is made in terms of ignition delays and the rate of heat release at three different IQT test temperatures.

Surrogates for JP-8 have been developed in the high temperature gas phase environment of gas turbines. In diesel engines, the fuel is introduced in the liquid phase where volatility plays a major role in the formation of the combustible mixture and autoignition reactions that occur at relatively lower temperatures. In this paper, the role of volatility on the combustion of JP-8 and five different surrogate fuels was investigated in the constant volume combustion chamber of the Ignition Quality Tester (IQT). IQT is used to determine the derived cetane number (DCN) of diesel engine fuels according to ASTM D6890. The surrogate fuels were formulated such that their DCNs matched that of JP-8, but with different volatilities. Tests were conducted to investigate the effect of volatility on the autoignition and combustion characteristics of the surrogates using a detailed analysis of the rate of heat release immediately after the start of injection.

This paper presents the results of an experimental investigation on a single cylinder engine to validate a two-component JP-8 surrogate. The two-component surrogate was chosen based on a previous investigation where the key properties, such as DCN, volatility, density, and lower heating value, of the surrogate were matched with those of the target JP-8. The matching of the auto-ignition, combustion, and emission characteristics of the surrogate with JP-8 was investigated in an actual diesel engine environment. The engine tests for the validation of the surrogate were conducted at an engine speed of 1500 rpm, a load of 3 bar, and different injection timings. The results for the cylinder gas pressure, ignition delay period, rate of heat release, and the CO, HC, and NOx emissions showed a good match between the surrogate and the target JP-8. However, the engine-out particulate matter for the surrogate was lower than that for the JP-8 at all tested conditions.

This paper investigates the effect of boost pressure and intake temperature on the auto-ignition of fuels with a wide range of properties. The fuels used in this investigation are ULSD (CN 45), FT-SPK (CN 61) and two blends of JP-8 (with CN 25 and 49). Detailed analysis of in-cylinder pressure and rate of heat release traces are made to correlate the effect of intake pressure and injection strategy on the events immediately following start of injection leading to combustion. A CFD model is applied to track the effect of intake pressure and injection strategy on the formation of different chemical species and study their role and contribution in the auto-ignition reactions. Results from a previous investigation on the effect of intake temperature on auto-ignition of these fuels are compared with the results of this investigation.