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In recent years, there has been rapid progress in characterizing the detailed chemical kinetics associated with the oxidation of liquid hydrocarbons and their blends. However adding these fuel models to the industrial engineer's toolkit has proven a major challenge due to issues associated with high CPU cost and the poor suitability of many of the most promising and well known fuel models to IC engine applications. This paper demonstrates the state-of-the-art in the analysis and modelling of current and future transportation fuels or fuel blends for internal combustion engine applications. First-of-all, a benchmarking of eleven representative fuel models (39 to 1034 species in size) is carried out at engine/engine-like operating conditions by adopting the standard Research Octane and Cetane Number test data for comparison. Next, methods to construct a fuel model for a commercial fuel are outlined using a simple, yet robust surrogate mapping technique.

Regulations on emissions from diesel and gasoline fuelled engines are becoming more stringent in all parts of the world. Hence there is a great deal of interest in developing advanced combustion systems that offer the efficiency of a diesel engine, but with low PM and NOx. One promising approach is that of Partially-Premixed Compression Ignition (PPCI) or Low Temperature Combustion (LTC). Using this approach, PM can be reduced in compression ignition engines by promoting the mixing of fuel and air prior to combustion. This paper describes the application of an advanced combustion simulator for fuels, combustion and emissions to analyze the key processes which occur in PPCI combustion mode. A detailed chemical kinetic model with advanced PM population balance sub-model is employed in a PPCI engine context to examine the impact of ignition resistance on combustion, mixing, ignition and emissions.