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This experimental study examines the effect on performance and emission outputs of a compression ignition engine operating on biodiesels of varying carbon chain length and the degree of unsaturation. A well-instrumented, heavy-duty, multi-cylinder, common-rail, turbo-charged diesel engine was used to ensure that the results contribute in a realistic way to the ongoing debate about the impact of biofuels. Comparative measurements are reported for engine performance as well as the emissions of NOx, particle number and size distribution, and the concentration of the reactive oxygen species (which provide a measure of the toxicity of emitted particles). It is shown that the biodiesels used in this study produce lower mean effective pressure, somewhat proportionally with their lower calorific values; however, the molecular structure has been shown to have little impact on the performance of the engine.

Air travel has continued to increase dramatically and all indications are that the rapid rate, approximately 4% per annum, will continue into the foreseeable future. One major barrier to this growth is related to fuel. There exist major technical challenges in supplying fuels and in reducing exhaust pollutants. Transport propulsion is dependent on limited sources, mainly fossil fuels, which have a peak production predicted to be around 2005, and crude oil sources are limited and will eventually run out. Commercial air transport is responsible for around 700 million tons of jet-fuel derived CO₂ today, about 2.31% of total anthropogenic carbon dioxide, future forecasts of aviation growth show CO₂ emissions from the sector rising rapidly and inexorably to more than 1 billion tons by 2025 and this is unlikely to be acceptable.