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A system for both ignition and ion current measurement was designed and set up at Istituto Motori. Particular attention was paid to the problem of dissipating the residual energy stored in the ignition coil, reducing the electromagnetic interferences and especially improving the response of the measurement system. In order to assess the capability of the ion current signal to give reliable and accurate information for knock detection, a number of tests were carried out at full load on a commercial PFI four cylinder engine, at various air/fuel ratios and spark timings. Some knock indices based on the ionization signal, both band pass filtered and non-filtered, were introduced, in particular: the Amplitude of the Second Ionization Peak (ASIP), the Mean not filtered Ionization Current signal (MIC), the Maximum Amplitude of Ionization Current signal Oscillation (MAICO), the Integral of Modulus of filtered Ionization Current signal Oscillation (IMICO).