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The nitrogen dioxide (NO₂) emissions of compression ignition diesel engines are usually relatively small, especially when operated at medium and high loads. Recent experimental investigations have suggested that adding hydrogen (H₂) into the intake air of a diesel engine leads to a substantial increase in NO₂ emissions. The increase in NO₂ fraction in the total NOx is more pronounced at lower engine load than at medium- and high-load operation, especially when a small amount of H₂ is added. However, the chemistry causing the increased NO₂ formation in H₂-diesel dual-fuel engines has not been fully explored. In the present work, kinetics of NO and NO₂ formation in a H₂-diesel dual-fuel engine are investigated using a CFD model integrated with a reduced hydrocarbon oxidation chemistry and an oxides of nitrogen (NOx) formation mechanism. A low-load and a medium-load operating condition are selected for numerical simulations.