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The use of thermo-electric (TE) generation systems in internal combustion engines (ICEs) to reduce the carbon dioxide emission by harnessing the exhaust thermal energy is showing increasing promise. In addition, integration with after treatment devices is a development route for this technology that offers a great potential. Recent work on TE systems have shown that the overall efficiency of present TE generation systems are constrained by, the limitations of the conversion efficiency and operating temperatures of TE materials; fabrication quality, durability and thermal performance of the thermo-electric modules (TEMs); geometrical configuration and heat exchange efficiency of thermo-electric generator (TEG) and; conversion techniques of the TEG's electrical output to a form suitable for vehicle systems.

Recent work on thermo-electric (TE) systems has highlighted the need for refined heat transfer design as well as the long standing need for improved materials performance. Recent work on heat transfer for TE systems has shown that enhanced heat transfer is needed over and above what would normally be seen in a vehicle exhaust system. In particular a better understanding of flow development and boundary layer behaviour is needed to support new design proposals. In the meantime, recent work in TE materials suggests that with the use of skutterudites significant performance benefits can accrue over existing materials. The current generation of TE materials have non-dimensional thermoelectric figure of merit (ZT) values of around 1. Skutterudites have been demonstrated to have ZT values of about 1.4 and can maintain these values over a wider temperature range than do existing materials through the engineering of the TE device.

The promise of thermo-electric (TE) technology in vehicles is a low maintenance solid state device for power generation. The Thermo-Electric Generator (TEG) will be located in the exhaust system and will make use of an energy flow between the warmer exhaust gas and the external environment. The potential to make use of an otherwise wasted flow of energy means that the overall system efficiency can be improved substantially. One of the barriers to a successful application of the technology is the device efficiency. The TE properties of even the most advanced materials are still not sufficient for a practical, cost effective device. However the rate of development is such that practical devices are likely to be available within the next fifteen years. In a previous paper [ 1 ], the potential for such a device was shown through an integrated vehicle simulation and TEG model.