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As a result of WNTE regulations and the introduction of close-coupled aftertreatment systems, exhaust purification at high temperatures in commercial vehicles has become increasingly important in recent years. In this report, we improve the prediction accuracy for NOx conversion at high temperatures in the kinetic model of conventional Cu-selective catalytic reduction (Cu-SCR). Reaction rate analysis indicated that the rate of NH3 oxidation was extremely low compared to the rate of standard SCR. We found that NOx concentration-dependent NH3 oxidations (termed NOx-assisted NH3 oxidations) were key to the rate of NH3 oxidation. The output of the improved Cu-SCR kinetic model was in agreed with experimental results obtained from the synthetic gas bench and engine dynamometer bench. We analyzed the contribution of each reaction to NH3 consumption during Cu-SCR. Under NH3 + NO + O2, standard SCR was dominant at low temperature.

A highly robust Diesel Oxidation Catalyst (DOC) for use with a dual mode combustion system, which makes it possible to switch the combustion between conventional mode and PCI (Premixed Compression Ignition) Combustion mode, was studied. Firstly, commercially available DOCs were tested to confirm current level of emission reduction efficiency for a simulated dual mode combustion system, where CO (Carbon monoxide) was varied from 500 to 5,000 ppm, HC (Hydrocarbon) was varied from 500 to 5,000 ppmC and O2 (Oxygen) was varied from 2 to 15%, respectively. A commercially available Pt based DOC showed good CO and HC light-off performance at 500 ppm of CO and HC at up to 10% O2. However, it did not keep the superior light-off activity when CO and HC were increased to 5,000 ppm and O2 was decreased to 2%. A commercially available Pt-Pd based DOC demonstrated better light-off activity compared to the Pt based DOC at lower CO and HC concentrations.