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The vast stores of biomass available worldwide have the potential to displace significant amounts of petroleum fuels. Fast pyrolysis of biomass is one of several possible paths by which we can convert biomass to higher value products. Pyrolysis oil (PO) derived from wood has been regarded as an alternative fuel to be used in diesel engines. However, the use of PO in a diesel engine requires engine modifications due to the low energy density, high acidity, high viscosity, high water content, and low cetane number of PO. The easiest way to adopt PO without engine modifications is blending with other fuels that have a high cetane number. However, PO has poor miscibility with light petroleum fuel oils; the most suitable candidate fuels for direct fuel mixing are alcohol fuels. Early mixing with alcohol fuels has the added benefit of significantly improving the storage and handling properties of the PO.

The vast stores of biomass available worldwide have the potential to displace significant amounts of petroleum fuels. Fast pyrolysis of biomass is one of several possible paths by which we can convert biomass to higher value products. Pyrolysis oil (PO) derived from wood has been regarded as an alternative fuel to be used in diesel engines. However, the use of PO in a diesel engine requires engine modifications due to the low energy density, high acidity, high viscosity, and low cetane number of PO. Therefore, PO should be blended or emulsified with other fuels that have a high cetane number or used through pilot injection. PO has poor miscibility with light petroleum fuel oils; the most suitable candidate fuels for direct fuel mixing are alcohol fuels. Early mixing with alcohol fuels has the added benefit of significantly improving the storage and handling properties of the PO.

Nowadays, automobile manufacturers are focusing on reducing exhaust-gas emissions because of their harmful effects on humans and the environment, such as global warming due to greenhouse gases. Direct injection combustion is a promising technology that can significantly improve fuel economy compared to conventional port fuel injection spark ignition engines. However, previous studies indicate that relatively high levels of nitrogen oxide (NOx) emission were produced with gasoline fuel in a spray-guided-type combustion system as a result of the stratified combustion characteristics. Because a lean-burn engine cannot employ a three-way catalyst, NOx emissions can be an obstacle to commercializing a lean-burn direct injection engine. Liquefied petroleum gas (LPG) fuel was proposed as an alternative for reducing NOx emission because it has a higher vapor pressure than gasoline and decreases the local rich mixture region as a result of an improved mixing process.

Combustion and emission characteristics of LPG(Liquefied Petroleum Gas) and gasoline fuels were compared in a single cylinder engine with direct fuel injection. While fuel injection pressure and IMEP(indicated mean effective pressure) were varied with 60, 90, 120 bar and 2 to 10 bar, another parameters for the engine operation as engine speed, air excess, and fuel injection timing were fixed at 1500 rpm, 1.0, and BTDC 300 CA respectively. Experimental results showed that MBT timing for LPG was less sensitive to IMEP, and high injection pressure made combustion stability worse at IMEP=2 bar. Through heat release analysis LPG showed shorter 10 and 90% MBD(mass burn duration) than gasoline due to fast flame speed and for both fuels injection pressure hardly affected burn duration. It was also found that thermal efficiency of LPG had a little higher than that of gasoline. Hydrocarbon emissions of gasoline rose to a level of three-fold than those of LPG.

The combustion and exhaust emission characteristics of a DME fueled HCCI engine were investigated. Different fuel injection strategies were tested under various injection quantities and timings with exhaust gas recirculation (EGR). The combustion phase in HCCI was changed by an in-cylinder direct injection and EGR, due to changes in the in-cylinder temperature and mixture homogeneity. The gross indicated mean effective pressure (IMEPgross) increased and the hydrocarbon (HC) and carbon monoxide (CO) emissions decreased as the equivalence ratio was augmented. The IMEPgross with direct injection was greater than with the port injection due to retarded ignition timing resulting from latent heat of direct injected DME fuel. It was because that most of burn duration was completed before top dead center owing to higher ignitability for DME with high cetane number. However, HC and CO emissions were similar for both injection locations.

Exhaust gas recirculation (EGR) and lean burn utilize the diluents into the engine cylinder to control combustion leading to enhanced fuel economy and reduced emissions. However, the occurrence of excessive cyclic variation with high diluent rates, brings about an undesirable combustion instability within the engine cylinder resulting in the deterioration of both engine performance and emissions. Proper stratification of mixture and diluents could improve the combustion stability under high diluent environment. EGR stratification within the cylinder was made by adopting a fast-response solenoid valve in the midst of EGR line and controlling its timing and duty. With EGR in both homogeneous mode and stratified mode, in-cylinder pressure and emissions were measured. The thermodynamic heat release analysis showed that the burning duration was decreased in case of stratified EGR. It was found that the stratification of EGR hardly affected the emissions.

An 11L heavy duty LPG MPI engine has been developed using the liquid phase LPG injection system, which is one of the next generation LPG fueling technologies, since the LPG MPI engine can achieve the higher power and efficiency, and lower exhaust emissions than the conventional mixer type system. Two prototypes - a natural aspiration(NA) engine and a turbocharged inter-cooler(TCI) engine - were developed in this work and tested to measure the performance and emissions. For a NA type engine, in order to achieve the low emissions, the stoichiometric air/fuel ratio was adapted with a three-way catalytic converter. Whereas, for a TCI type, the lean burn technology was introduced to minimize the thermal loading due to an increase of the engine power. The results in this work demonstrated that the LPG MPI engines have the higher engine performance and lower exhaust emissions than the base diesel engine.

An LPG engine for heavy duty vehicles has been developed using liquid phase LPG injection (hereafter LPLI) system, which has regarded as as one of next generation LPG fuel supply systems. In this work the optimized piston cavities were investigated and chosen for an LPLI engine system. While the mass production of piston cavities is considered, three piston cavities were tested: Dog-dish type, bathtub type and top-land-cut bathtub type. From the experiments the bathtub type showed the extension of lean limit while achieving the stable combustion, compared to the dog-dish type at the same injection timing. Throughout CFD analysis, it was revealed that the extension of lean limit was due to an increase of turbulence intensity by the enlarged crevice area, and the enlargement of flame front surface owing to the shape of the bathtub piston cavity compared to that of the dog-dish type.

A LPG engine for heavy duty vehicle has been developed using liquid phase LPG injection (hereafter LPLI) system, which has a strong potential as a next generation LPG fuel supply system. It has been revealed in this work that an LPLI system generates higher power, efficiency, and emits lower emission pollutants than the conventional mixer type system. As a preliminary study on the LPLI system applicable to a heavy duty LPG engine, the engine output and combustion performance were investigated with various operating conditions using a single cylinder engine equipped with the different fuel supply systems. Experimental results showed that no problems occurred and the volumetric efficiency and engine output increased, respectively by about 10%, when the LPLI system is used. A decrease of the intake manifold temperature by the LPLI system has also been observed.