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Technical Paper

Alternative to Hydrogen/Helium as Flame Ionization Detector Fuel

2013-04-08
2013-01-1045
Flame ionization detector (FID) analyzers used in emission testing to measure total hydrocarbon emissions have been operating for the last forty years on a fuel mixture of 40% H₂ and 60% helium. These mixtures were selected based on research studies reported in the literature indicating that this particular mixed fuel combination gave the best sensitivity and relative response of the different hydrocarbons present in vehicle exhaust with respect to propane, the calibration gas. During the past few years, it was announced that there is a worldwide shortage of helium which triggered the automotive industry to look for alternatives for helium to be used in FID fuels. Helium which is produced as a byproduct from natural gas fields is non-renewable, expensive, and extremely rare on the earth. Current supply cannot keep up with demand. There are only few natural gas fields producing helium and unless new natural gas fields are found, current helium amounts will continue to dwindle.
Technical Paper

Integration of Photoacoustic Innova Analyzer Within Bag Bench for Direct Measurement of Ethanol in Vehicle Emissions

2009-04-20
2009-01-1518
Ethanol fuel is a sustainable energy resource intended to provide a more environmentally and economically friendly alternative to fossil fuels. Ethanol fuel for automotive applications is becoming increasingly widespread and its market is continuing to grow. Measurement of ethanol was traditionally done with an impinger and a gas chromatograph (GC) system but this method is not a direct measurement, usually requires manual handling and takes a long time for post processing of data. The Innova photoacoustic analyzer can directly measure the ethanol emissions in vehicle exhaust without using the impinger/GC system. For the past eight years at Chrysler, the Innova has been used as a stand alone analyzer and the emission sample bags were physically transported to the chemistry lab for ethanol measurement. The data had to be manually entered and post processed for the final results.
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