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The optimal fuel for partially premixed combustion (PPC) is considered to be a gasoline boiling range fuel with an octane number around 70. Higher octane number fuels are considered problematic with low load and idle conditions. In previous studies mostly the intake air temperature did not exceed 30 °C. Possibly increasing intake air temperatures could extend the load range. In this study primary reference fuels (PRFs), blends of iso-octane and n-heptane, with octane numbers of 70, 80, and 90 are tested in an adapted commercial diesel engine under partially premixed combustion mode to investigate the potential of these higher octane number fuels in low load and idle conditions. During testing combustion phasing and intake air temperature are varied to investigate the combustion and emission characteristics under low load and idle conditions.

In this work, the influences of aromatics on combustion and emission characteristics from a heavy-duty diesel engine under various loads and exhaust gas recirculation (EGR) conditions are investigated. Tests were performed on a modified single-cylinder, constant-speed and direct-injection diesel engine. An engine exhaust particle sizer (EEPS) was used in the experiments to measure the size distribution of engine-exhaust particle emissions in the range from 5.6 to 560 nm. Two ternary blends of n-heptane, iso-octane with either toluene or benzaldehyde denoted as TRF and CRF, were tested, diesel was also tested as a reference. Test results showed that TRF has the longest ignition delay, thus providing the largest premixed fraction which is beneficial to reduce soot. However, as the load increases, higher incylinder pressure and temperature make all test fuels burn easily, leading to shorter ignition delays and more diffusion combustion.

Numerous previous studies have reported that the reduction of emissions by adapting oxygenated bio-fuels chiefly depend on the overall oxygen percentage of the blended oxygenates. However, the effect of molecular structures of the fuels has sometimes only been attributed to differences in auto-ignition quality (i.e. cetane number). In this paper, fuels with two kinds of molecular structures, namely linear and cyclic, have been studied. It reports on emissions tests on a modified in-line 6-cylinder DAF HD Diesel engine with several selected oxygenates mixed with diesel. Fuels in question here are from the non-oxygenates group: n-hexane and cyclohexane, and the oxygenate group: 1-hexanol and cyclohexanol. In order to isolate the effect of molecular structure, the blend compositions are chosen such that the overall oxygen fraction of all blends is the same.

Styrene, or ethylbenzene, is mainly used as a monomer for the production of polymers, most notably Styrofoam. In the synthetis of styrene, the feedstock of benzene and ethylene is converted into aromatic oxygenates such as benzaldehyde, 2-phenyl ethanol and acetophenone. Benzaldehyde and phenyl ethanol are low value side streams, while acetophenone is a high value intermediate product. The side streams are now principally rejected from the process and burnt for process heat. Previous in-house research has shown that such aromatic oxygenates are suitable as diesel fuel additives and can in some cases improve the soot-NOx trade-off. In this study acetophenone, benzaldehyde and 2-phenyl ethanol are each added to commercial EN590 diesel at a ratio of 1:9, with the goal to ascertain whether or not the lower value benzaldehyde and 2-phenyl ethanol can perform on par with the higher value acetophenone. These compounds are now used in pure form.

In an earlier study, a novel type of diesel fuel injector was proposed. This prototype injects fuel via porous (sintered) micro pores instead of via the conventional 6-8 holes. The micro pores are typically 10-50 micrometer in diameter, versus 120-200 micrometer in the conventional case. The expected advantages of the so-called Porous Fuel Air Mixing Enhancing Nozzle (PFAMEN) injector are lower soot- and CO2 emissions. However, from previous in-house measurements, it has been concluded that the emissions of the porous injector are still not satisfactory. Roughly, this may have multiple reasons. The first one is that the spray distribution is not good enough, the second one is that the droplet sizing is too big due to the lack of droplet breakup. Furthermore air entrainment into the fuel jets might be insufficient. All reasons lead to fuel rich zones and associated soot formation.

Partially Premixed Combustion has shown the potential of low emissions of nitrogen oxides (NOx) and soot with a simultaneous improvement in fuel efficiency. Several research groups have shown that a load range from idle to full load is possible, when using low-octane-number refinery streams, in the gasoline boiling range. As such refinery streams are not expected to be commercially available on the short term, the use of naphtha blends that are commercially available could provide a practical solution. The three blends used in this investigation have been tested in a single-cylinder engine for their emission and efficiency performance. Besides a presentation of the sensitivity to injection strategies, dilution levels and fuel pressure, emission performance is compared to legislated emission levels. Conventional diesel combustion benchmarks are used for reference to show possible improvements in indicated efficiency.

Partially Premixed Combustion has shown the potential of high efficiency, emissions of nitrogen oxides (NOx) and soot below future emissions regulations, and acceptable acoustic noise. Low-octane-number gasoline fuels were shown to be most suitable for this concept, with the reactivity determining the possible load range. Other researchers have used several refinery streams, which might be produced by a refinery if they were required to do so without additional investment. Some of refinery streams are, however, not expected to be commercially available on the short term. For the present investigation, n-butanol (BuOH) has been selected as a blend component in diesel, and is used from 50 - 100%. The blends then have a reactivity range similar to the refinery streams, so single-cylinder engine tests for their emission and efficiency performance can also be used to determine their applicable load range.

The wide range of diesel engine operating conditions demand for a robust combustion model to account for inherent changes. In this work, the Flamelet Generate Manifold (FGM) approach is applied, in STAR-CD framework, to simulate the conventional injection- and early injection-timing (PCCI like) combustion regimes. Igniting Counter flow Diffusion Flamelets (ICDFs) and Homogeneous Reactors (HRs) are used to tabulate chemistry for conventional and PCCI combustion modes, respectively. The validation of the models with experimental data shows that the above consideration of chemistry tabulation results in accurate ignition delay predictions. The study reveals that a moderate amount of 5 different pressure levels is necessary to include in the FGM database to capture the ignition delay in both combustion regimes.

Mixing is inhibited both by the relatively low volatility of conventional diesel fuel and the short premixing time due to high fuel reactivity (i.e. cetane number (CN)). Consequently, in this research two promising oxygenates which can be produced from 2nd generation biomass -ethanol from cellulose and anisole from lignin - will be blended to gasoline, further doped with ignition improver. This will result in a diesel-like CN, but with a higher gasoline-like volatility. There is, however, also a more practical motivation for this study. In Europe, the dieselization trend is resulted in a growing excess of gasoline, which is currently largely exported to the USA at additional transport costs. Boosting the cetane number of gasoline into the diesel range with ignition improvers is a promising route to more efficiently consume European refinery products within Europe.

In this paper, the soot-NOx trade-off and fuel efficiency of various aromatic oxygenates is investigated in a modern DAF heavy-duty diesel engine. All oxygenates were blended to diesel fuel such that the blend oxygen concentration was 2.59 wt.-%. The oxygenates in question, anisole, benzyl alcohol and 2-phenyl ethanol, have similar heating values and cetane numbers, but differ in the position of the functional oxygen group relative to the aromatic ring. The motivation for this study is that in lignin, a widely available and low-cost biomass feedstock, similar aromatic structures are found with varying position of the oxygen group to the aromatic ring. From the results it becomes clear that both the soot-NOx trade-off and the volumetric fuel economy (i.e. ml/kWh) is improved for all oxygenates in all investigated work points.

To improve the mixing of fuel and air in the combustion chamber of current diesel engines, research is carried out regarding injectors with a porous nozzle tip, replacing conventional nozzles with a limited number of holes. Preliminary tests with porous injectors showed that further research concerning spray distribution was necessary due to non-optimal spray shapes and low fuel velocities. Therefore, spray shapes and fuel velocities of porous injectors were examined at atmospheric pressures. These examinations show that the spray shapes can be adjusted by alternating the geometries. Geometrical influences have been studied and compared to conventional injectors, showing that the fuel velocity of the porous injectors has decreased with approximately a factor of 10. Subsequently, research concerning the lifetime of porous nozzles was necessary due to premature failure.

Controlling ignition delay is the key to successfully enable partially premixed combustion in diesel engines. This paper presents experimental results of partially premixed combustion in an optically accessible engine, using primary reference fuels in combination with artificial exhaust gas recirculation. By changing the fuel composition and oxygen concentration, the ignition delay is changed. To determine the position of the flame front, high-speed visualization of OH-chemiluminescence is used, enabling a cycle-resolved analysis of OH formation. A clear correlation is observed between ignition delay and flame location. The mixing of fuel and air during the ignition delay period defines the local equivalence ratio, which is estimated based on a spherical combustion volume for each spray. The corresponding emission measurements using fast-response analyzers of CO, HC and NOX confirm the decrease in local equivalence ratio as a function of ignition delay.

The Flamelet Generated Manifold (FGM) method is a promising technique in engine combustion modeling to include tabulated chemistry. Different methodologies can be used for the generation of the manifold. Two approaches, based on igniting counterflow diffusion flamelets (ICDF) and homogeneous reactors (HR) are implemented and compared with Engine Combustion Network (ECN) experimental database for the baseline n-heptane case. Before analyzing the combustion results, the spray model is optimized after performing a sensitivity study with respect to turbulence models, cell sizes and time steps. The standard High Reynolds (Re) k-ε model leads to the best match of all turbulence models with the experimental data. For the convergence of the mixture fraction field an appropriate cell size is found to be smaller than that for an adequate spray penetration length which appears to be less influenced by the cell size.

In earlier research, a new class of bio-fuels, so-called cyclic oxygenates, was reported to have a favorable impact on the soot-NOx trade-off experience in diesel engines. In this paper, the soot-NOx trade-off is compared for two types of cyclic oxygenates. 2-phenyl ethanol has an aromatic and cyclohexane ethanol a saturated or aliphatic ring structure. Accordingly, the research is focused on the effect of aromaticity on the aforementioned emissions trade-off. This research is relevant because, starting from lignin, a biomass component with a complex poly-aromatic structure, the production of 2-phenyl ethanol requires less hydrogen and can therefore be produced at lower cost than is the case for cyclohexane ethanol.

Recently, some studies have shown high efficiencies using controlled auto-ignition by blending gasoline and diesel to a desired reactivity. This concept has been shown to give high efficiency and, because of the largely premixed charge, low emission levels. The origin of this high efficiency, however, has only partly been explained. Part of it was attributed to a lower temperature combustion, originating in lower heat losses. Another part of the gain was attributed to a faster, more Otto-like (i.e. constant volume) combustion. Since the concept was mainly demonstrated on one single test setup so far, an experimental study has been performed to reproduce these results and gain more insight into their origin. Therefore one cylinder of a heavy duty test engine has been equipped with an intake port gasoline injection system, primarily to investigate the effects of the balance between the two fuels, and the timing of the diesel injection.

Increasing fuel prices keep bringing attention to alternative, cheaper fuels. Liquefied Petroleum Gas (LPG) has been well known for decades as an alternative fuel for spark ignition (SI) passenger cars. More recently, aftermarket LPG systems were also introduced to Heavy Duty transport vehicles. These (port fuel) systems either vaporize the liquid fuel and then mix it with intake air, or inject fuel into the engine's intake ports. While this concept offers significant fuel cost reductions, for aftermarket certification and large-scale OEM use some concerns are present. Unburned hydrocarbons (UHC) and carbon monoxide (CO) emissions are known to be high because of premixed charge getting trapped into crevices and possibly being blown through during valve-overlap. Apart from the higher emission levels, this also limits fuel efficiency and therefore cost savings.

A study on the modeling of fuel sprays in diesel engines will be presented. First, modeling of non-reacting diesel spray formation is studied in Fluent and Star-CD. The main objective however is to model combustion of the spray using a generic approach. This is achieved by applying a detailed chemistry tabulation method, called FGM (Flamelet Generated Manifold). Using this approach will make additional ignition modeling, which is conventional, obsolete. The FGM method is implemented in Fluent and Star-CD. Subsequently, constant volume spray combustion and full engine cycle simulations are performed. Spray formation is modeled with Lagrangian type models that are available in Fluent and Star-CD, and also with a 1D Euler-Euler spray model that is implemented and applied in 3D Fluent simulations. The results are compared with EHPC (Eindhoven High Pressure Cell) experiments, data from Sandia National Laboratories and IFP (Institut Français du Pétrole).