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During the past decades, the Nitrogen Oxides (NOx) emission limitations have become stricter, promoting the development of after-treatment systems like Selective Catalytic Reduction (SCR) for emission reduction purposes. The Urea-Water Solution (UWS) spray characteristics can directly have an effect on the SCR efficiency. To understand the droplet breakup and mixing of the UWS with the surrounding air under different operating conditions, a computational campaign has been set up. The main objective of the present study is to recreate the spray injection process, as well as the chemical processes that the UWS spray undergoes, and to analyze the optimal injection angle to maximize the amount of ammonia generated during the injection process by means of Computational Fluid Dynamics (CFD). A Eulerian-Lagrangian framework has been employed to track the evolution of the injected droplets within a Reynolds-Averaged Navier-Stokes (RANS) turbulence formulation.

Selective Catalytic Reduction stands for an effective methodology for the reduction of NOx emissions from Diesel engines and meeting current and future EURO standards. For it, the injection of Urea Water Solution (UWS) plays a major role in the process of reducing the NOx emissions. A LES approach for turbulence modelling allows to have a description of the physics which is a very useful tool in situations where experiments cannot be performed. The main objective of this study is to predict characteristics of the flow of interest inside the injector as well as spray morphology in the near field of the spray. For it, the nozzle geometry has been reconstructed from X-Ray tomography data, and an Eulerian-Eulerian approach commonly known as Mixture Model has been applied to study the liquid phase of the UWS with a LES approach for turbulence modeling. The injector unit is subjected to typical low-pressure working conditions.

The Selective Catalytic Reduction (SCR) system has great potential in reducing NOx emissions. The urea-water solution (UWS) is the preferred method on vehicles for obtaining the ammonia, the required reductant for SCR. The UWS spray is necessary to transform exhaust gas into nitrogen and water and plays an important role in the performance of this system. The UWS needs to be properly mixed with the exhaust gas coming from the engine before entering the SCR, therefore the solution must be injected in the exhaust pipe in a way that it completely vaporizes in order to reduce deposit formation and guaranteeing a proper functioning and durability of the NOx reduction system. Achieving complete vaporization of the UWS spray is not an easy task, mainly due to reduced package space. Another challenge for converting UWS to ammonia is the latent energy in the exhaust.

In the present work a constant-pressure flow facility able to reach 15 MPa ambient pressure and 1000 K ambient temperature has been employed to carry out experimental studies of the combustion process at Diesel engine like conditions. The objective is to study the effect of orifice diameter on combustion parameters as lift-off length, ignition delay and flame penetration, assessing if the processing methodologies used for a reference nozzle are suitable in heavy duty applications. Accordingly, three orifice diameter were studied: a spray B nozzle, with a nominal diameter of 90 μm, and two heavy duty application nozzles (diameter of 194 μm and 228 μm respectively). Results showed that nozzle size has a substantial impact on the ignition event, affecting the premixed phase of the combustion and the ignition location. On the lift-off length, increasing the nozzle size affected the combustion morphology, thus the processing methodology had to be modified from the ECN standard methodology.

Starting and operating of diesel engines in cold conditions is a common and important problem. Many factors such as ambient conditions, fuel properties, fuel injection, cranking speed, etc, affect cold engine functionality. In order to improve diesel engine cold start, it is essential to understand better these problems. In this paper the injection development at cold temperatures is studied, since it is an important parameter that affects the fuel interaction with the air, so the future combustion process would also be influenced. In particular, a hydraulic characterization of diesel injection is made, using specialized test rigs that simulate real engine in-cylinder air pressure and density; the fuel is injected from three axi-symmetric convergent nozzles at several injection pressures (30, 50, 80, 120 and 180 MPa), two chamber densities and two temperatures of 255 K (winter) and 298 K (reference).