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Technical Paper

The Impact of Fuel Sulfur and Catalyst PGM Loadings on the Emissions of a PZEV 4 Cylinder Vehicle

2017-10-08
2017-01-2404
Federal Test Procedure (FTP) emissions were measured on a 2009 4 cylinder 2.4L Malibu PZEV vehicle with 10 and 30ppm sulfur fuel while varying the PGM (Platinum Group Metals) of the close-coupled and underfloor converters. Base CARB PH-III certification fuel was used. Three consecutive FTPs were used to measure the impact of fuel sulfur and catalyst PGM loading combinations. In general, reducing fuel sulfur and increasing catalyst PGM loadings, decrease FTP emissions. Increasing Pd concentrations can mitigate the impact of higher fuel sulfur concentrations. The results also suggest that a 50% reduction in PGM can be achieved with a reduction in fuel sulfur from 30 to 10 ppm. On average, NMHC, CO and NOx emissions were reduced by 12, 49 and 64%, respectively with the 10 ppm sulfur fuel. In addition, HC and NOx vehicle emission variability were reduced by 74 and 57% with the 10 ppm sulfur fuel.
Journal Article

N2O Emissions of Low Emission Vehicles

2013-04-08
2013-01-1300
The Environmental Protection Agency (EPA) and Department of Transportation's National Highway Traffic Safety Administration (NHTSA) have finalized regulation that will reduce greenhouse gases and increase fuel economy for model year (MY) 2012-2016 light-duty vehicles. This ruling not only includes a CO₂ standard that will require vehicles to achieve fleet average 35 mpg by MY 2016, but will apply a cap on nitrous oxide (N₂O) and methane emissions to 10 and 30 mg/mile, respectively, however CO₂ emission reductions can be exchanged for either N₂O or methane credit. The work outlined investigates the N₂O emissions of a variety of low emission vehicles per the Federal Test Procedure (FTP). Fourier Transform Infrared Spectroscopy (FTIR) was used to measure both bag and modal N₂O emissions. N₂O emissions were less than 1 mg/mile for three SULEV vehicles with 6,400 km-aged catalysts.
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