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In order to meet LEV III, EURO 6C and Beijing 6 emission levels, Original Equipment Manufacturers (OEMs) can potentially implement unique aftertreatment systems solutions which meet the varying legislated requirements. The availability of various washcoat substrates and PGM loading and ratio options, make selection of an optimum catalyst system challenging, time consuming and costly. Design for Six Sigma (DFSS) methodologies have been used in industry since the 1990s. One of the earliest applications was at Motorola where the methodology was applied to the design and production of a paging device which Consumer Reports called “virtually defect-proof”.[1] Since then, the methodology has evolved to not only encapsulate complicated “Variation Optimization” but also “Design Optimization” where multiple factors are in play. In this study, attempts are made to adapt the DFSS concept and methodology to identify and optimize a catalyst for diesel applications.

The Three Way Catalyst (TWC) is an effective pollutant conversion system widely used in current production vehicles to satisfy emissions regulations. A TWC’s conversion efficiency degrades over time due to chemical and/or thermal mechanisms causing the catalyst to age. This reduction in conversion efficiency must be accounted for to ensure full useful life emissions compliance. This paper presents an experimental study of the aging impact on TWC performance. Four TWCs differentiated by their age, given in terms of miles driven, were tested. It is shown that the dynamics of oxygen storage are substantially affected by aging of the TWC. A previously developed physics-based oxygen storage model [1] is subsequently used to incorporate the effect of aging on the total Oxygen Storage Capacity (OSC). Parameter identification results for the different age catalysts show that total oxygen storage capacity decreases substantially with aging and is insensitive to operating conditions.

Significant reduction in Nitrogen Oxide (NOx) emissions will be required to meet LEV III/Tier III Emissions Standards for Light Duty Diesel (LDD) passenger vehicles. As such, Original Equipment Manufacturers (OEMs) are exploring all possible aftertreatment options to find the best balance between performance, durability and cost. The primary technology adopted by OEMs in North America to achieve low NOx levels is Selective Catalytic Reduction (SCR). The critical parameters needed for SCR to work properly are: an appropriate reductant such as ammonia (NH3) provided as Diesel Exhaust Fluid (DEF), which is an aqueous urea solution 32.5% concentration in weight with water (CO(NH2)2 + H2O), optimum operating temperatures, and optimum nitrogen dioxide (NO2) to NOx ratios (NO2/NOx). The NO2/NOx ratio is most influenced by Precious Group Metals (PGM) containing catalysts upstream of the SCR catalyst.

The ammonia slip catalyst (ASC), typically composed of Pt oxidation catalyst overlaid with SCR catalyst, is employed for the mitigation of NH3 slip originating from SCR catalysts. Oxidation and SCR functionalities in an ASC can degrade through two key mechanisms i) irreversible degradation due to thermal aging and ii) reversible degradation caused by sulfur-oxides. The impact of thermal aging is well understood and it mainly degrades the SCR function of the ASC and increases the NH3 conversion to undesired products [1]. This paper describes the impact of sulfur-oxides on critical functions of ASC and on NH3 oxidation activity and selectivity towards N2, NOx and N2O. Furthermore impact of desulfation under selected conditions and its extent of ASC performance recovery is explained.

New Particulate Matter (PM) and Particulate Number (PN) regulations throughout the world have created a need for aftertreatment solutions that include particulate control as an option to comply with the legislation. However, limitations in other criteria emissions cannot be sacrificed to accomplish the reduction of PM/PN. For this work, three-way washcoat catalyzed wall-flow Gasoline Particulate Filters (GPF) and similarly catalyzed flow-through catalysts of common defined volume were tested. Their catalytic performance was determined by measuring NOx, CO and HC conversion efficiencies and CO2 levels over the U.S. Federal Test Procedure 75 (FTP-75) and US06 Supplemental Federal Test Procedure (US06) cycles. Analysis of the impact on CO2 emissions was also evaluated in relation to backpressure from 1-D modeling analysis. All exhaust systems used the same loading and ratio of Platinum Group Metals (PGM), but employed different cell structures in their substrates.

Significant reduction in Nitrogen Oxide (NOx) emissions will be required to meet LEV III Emissions Standards for Light Duty Diesel passenger vehicles (LDD). As such, Original Equipment Manufacturers (OEMs) are exploring all possible aftertreatment options to find the best balance between performance, robustness and cost. The primary technology adopted by OEMs in North America to achieve low NOx levels is Selective Catalytic Reduction (SCR) catalyst. The critical parameters needed for SCR to work properly are: an appropriate reductant such as ammonia (NH3) typically provided as urea, adequate operating temperatures, and optimum Nitrogen Dioxide (NO2) to NOx ratios (NO2/NOx). The NO2/NOx ratio is mostly influenced by Precious Group Metals (PGM) containing catalysts located upstream of the SCR catalyst. Different versions of zeolite based SCR technologies are available on the market today and these vary in their active metal type (iron, copper, vanadium), and/or zeolite type.

Selective Catalytic Reduction (SCR) catalysts used in Lean NOx Trap (LNT) - SCR exhaust aftertreatment systems typically encounter alternating oxidizing and reducing environments. Reducing conditions occur when diesel fuel is injected upstream of a reformer catalyst, generating high concentrations of hydrogen (H₂), carbon monoxide (CO), and hydrocarbons to deNOx the LNT. In this study, the functionality of an iron (Fe) zeolite SCR catalyst is explored with a bench top reactor during steady-state and cyclic transient SCR operation. Experiments to characterize the effect of an LNT deNOx event on SCR operation show that adding H₂ or CO only slightly changes SCR behavior with the primary contribution being an enhancement of nitrogen dioxide (NO₂) decomposition into nitric oxide (NO). Exposure of the catalyst to C₃H₆ (a surrogate for an actual exhaust HC mixture) leads to a significant decrease in NOx reduction capabilities of the catalyst.

“Zoning” a catalytic converter involves placing higher concentrations of platinum group metals (PGM) in the inlet portion of the substrate. This is done to optimize the cost-to-performance tradeoff by increasing the reaction rate at lower temperatures while minimizing PGM usage. A potentially useful application of catalyst zoning is to improve performance using a constant PGM mass. A study was performed to assess what the optimum ratio of front to rear palladium zone length is to achieve the highest performance in vehicle emission testing. Varying the zone ratio from 1:1 to 1:9 shows a clear hydrocarbon performance optimum at a 1:5.66 (15%/85%) split. This performance optimum shows as both a minimum in FTP75 non-methane organic gas (NMOG) emissions as well as a minimum in hydrocarbon, carbon monoxide, and nitrogen oxide light-off temperature. Overall, an improvement of 18%, or 11 mg/mi of combined NMOG+NOx emissions was obtained without using additional PGM.