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Stochastic Preignition (SPI) is an abnormal combustion phenomenon for internal combustion engines (ICE), which has been a significant impact to automotive companies developing high efficiency, turbocharged, direct fuel injection, spark ignited engines. It is becoming clearer what fuel properties are related to the cause of SPI, whether directly with fuel preparation in the cylinder, or mechanisms related to the deposit build-up which contributes to initial and follow-on SPI events. The purpose of this paper is to provide a summary of global market gasoline fuel properties with special attention given to properties and specific compounds from the fuel and fuel additives that can contribute to SPI and the deposit build-up in engines. Based on a review of the global fuel quality, it appears that the fuel quality has not caught up to meet the technology requirements for fuel economy from modern technology engines.

A gasoline’s chemical composition impacts a vehicle’s sooting tendency and therefore has been the subject of numerous emissions studies. From these studies, several mathematical correlation equations have been developed to predict a gasoline’s sooting tendency in modern spark-ignited internal combustion engine vehicles. This paper reviews the recently developed predictive tool methods and summarizes five years of global market fuel survey data to characterize gasoline sooting tendency trends around the world. Additionally, the paper will evaluate and suggest changes to the predictive methods to improve emissions correlations.

The Particulate Matter Index (PMI) is a helpful tool which provides an indication of a fuel’s sooting tendency. Currently, the index is being used by various laboratories and OEMs as a metric to understand the gasoline range fuels impact on both sooting found on engine hardware and vehicle out emissions. This paper will explore a new method that could be used to give indication of the sooting tendency of the gasoline range fuels, with good correlation agreement to PMI. In addition, the paper will cover a global assessment of a gasoline range fuel’s sooting tendency based on the PMI number and the proposed method. Areas around the globe where market gasoline range fuels are of concern will be highlighted, in coordination with the new emissions regulations. Vehicle PM/PN data will also be presented that shows correlations of the indices to the vehicle response.

Biodiesel is a domestic, renewable fuel for diesel engines and is made from agricultural co-products such as soybean oil, rapeseed oil, palm oil and other natural oils. Biodiesel is a cleaner burning fuel that is biodegradable and non-toxic compared to petroleum diesel. Biodiesel has become a major alternative fuel for automotive applications and is critical for lowering US dependence on foreign oil and attain energy security. Vehicle manufacturers have developed new vehicle and diesel engine technologies compatible with B6-B20 biodiesel blends meeting ASTM D7467 specifications. Field warranty and validation tests have shown significant concerns with use of poor quality biodiesel fuels including fuel system deposits, engine oil deterioration, and efficiency loss of the after treatment system. Maintaining good quality of biodiesel is critical for success as a commercial fuel.

Ethanol for use in automotive fuels can be made from renewable feedstocks, which contributes to its increased use in recent years. There are many differences in physical and chemical properties between ethanol and petrochemicals refined from fossil oil. One of the differences is its energy content. The energy content, or heating value, is an important property of motor fuel, since it directly affects vehicle fuel economy. While the energy content can be measured by combustion of the fuel in a bomb, the test is time-consuming and expensive. It is generally satisfactory and more convenient to estimate that property from other commonly-measured fuel properties. Several standardized empirical methods have been developed in the past for estimating the energy content of hydrocarbon fuels such as gasoline, diesel fuel, and jet fuel.

Biodiesel has become a major alternative fuel for automotive applications demonstrated by its increasing presence in the market place. This paper summarizes test results for recently collected retail samples of biodiesel (B100) and blended biodiesel from the U.S. and the European Union to provide a snap shot of current fuel quality in each market. Properties reported included biodiesel content, oxidation stability, acid number, water, metals, and glycerin content. For B100, only total contamination measured as particulates was significantly lower for the EU than the U.S. For blends containing up to 5% biodiesel, there were significant differences between the U.S. and the EU in sulfur content, oxidation stability (Rancimat), cetane number, and cloud point. For blends higher than B5, present only in the U.S., pump labeling was found to be a poor indicator of biodiesel content.