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The European Commission (EC) as well as the United States Environmental Protection Agency (EPA) published legislations to regulate or encourage the use of low Global Warming Potential (GWP) refrigerants applied to Mobile Air Conditioning (MAC) systems. Europe mandates a GWP less than 150 of MAC refrigerants for new vehicle types. The thermodynamic refrigerant properties of R-1234yf are slightly different from the properties of R-134a, currently used in MAC systems. Although the basic material data show that R-1234yf is flammable, ignition tests performed for an automotive engine under-hood environment reveal design and packaging influences of its ignition behavior. After extensive collaborative research in 2009, the Society of Automotive Engineers Cooperative Research Team (SAE CRP1234) concluded that R-1234yf is suitable for use in automotive applications. Further ignition risk assessment regarding R-1234yf usage in MAC systems was done by SAE CRP1234-4 in 2013.

An evaluation methodology has been developed for assessing the suitability of R-1234yf in vehicles. This relates primarily to evaluating the flammability of R-1234yf in the engine compartment during a frontal collision. This paper will discuss the process followed in the methodology, the technical rationale for this process, and the results of the analysis. The specific types of analysis included in the methodology are: exhaust-system thermal characterization, computer simulated crash tests, actual crash tests, teardown and examination of crashed parts, and releases of refrigerant onto hot exhaust manifolds. Each type of analysis was logically ordered and combined to produce a comprehensive evaluation methodology. This methodology has been applied and demonstrates that R-1234yf is difficult to ignite when factors that occur in frontal crashes are simultaneously considered.