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To support the market introduction of lithium ion energy storage systems for HEV and EREV applications, a process and tool was developed to expedite the verification of the lithium-ion cell balancing system across differing usage scenarios and cell imbalance rates. Presented is an overview of the cell imbalance analysis methodology and tool used in the development and verification of General Motors cell balancing systems. The use of this analysis methodology and tool has allowed for a cell balancing system optimization that would not have been possible with the use of actual energy storage systems because of the magnitude of lab or vehicle time required to execute the array of tests necessary to comprehend the large number of factors than can influence balancing.