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Significant reduction in Nitrogen Oxide (NOx) emissions will be required to meet LEV III Emissions Standards for Light Duty Diesel passenger vehicles (LDD). As such, Original Equipment Manufacturers (OEMs) are exploring all possible aftertreatment options to find the best balance between performance, robustness and cost. The primary technology adopted by OEMs in North America to achieve low NOx levels is Selective Catalytic Reduction (SCR) catalyst. The critical parameters needed for SCR to work properly are: an appropriate reductant such as ammonia (NH3) typically provided as urea, adequate operating temperatures, and optimum Nitrogen Dioxide (NO2) to NOx ratios (NO2/NOx). The NO2/NOx ratio is mostly influenced by Precious Group Metals (PGM) containing catalysts located upstream of the SCR catalyst. Different versions of zeolite based SCR technologies are available on the market today and these vary in their active metal type (iron, copper, vanadium), and/or zeolite type.

Significant reduction in Nitrogen Oxide (NOx) emissions will be required to meet LEV III/Tier III Emissions Standards for Light Duty Diesel (LDD) passenger vehicles. As such, Original Equipment Manufacturers (OEMs) are exploring all possible aftertreatment options to find the best balance between performance, durability and cost. The primary technology adopted by OEMs in North America to achieve low NOx levels is Selective Catalytic Reduction (SCR). The critical parameters needed for SCR to work properly are: an appropriate reductant such as ammonia (NH3) provided as Diesel Exhaust Fluid (DEF), which is an aqueous urea solution 32.5% concentration in weight with water (CO(NH2)2 + H2O), optimum operating temperatures, and optimum nitrogen dioxide (NO2) to NOx ratios (NO2/NOx). The NO2/NOx ratio is most influenced by Precious Group Metals (PGM) containing catalysts upstream of the SCR catalyst.

To meet TierII/LEVII emissions standards, light duty diesel (LDD) vehicles require high conversion efficiencies from the Aftertreatment Systems (ATS) for the removal of both Hydrocarbon (HC) and Nitrogen Oxide (NOx) species. The most populous configuration for LDD ATS have the Selective Catalytic Reduction (SCR) catalyst positioned on the vehicle behind the close coupled Diesel Oxidation Catalyst (DOC) and Catalyzed Diesel Particulate Filter (CDPF). This SCR position may require active heating measures which rely on the DOC/CDPF to provide heat through the combustion of HC and CO in the exhaust. Although DOCs are always impacted by their aging conditions, some aging conditions are shown to be both reversible and irreversible.

Stringent global emissions legislations demand effective NOx reduction strategies for both the engine as well as the aftertreatment. Diesel applications have previously applied Lean NOx Catalysts (LNCs) [1, 2], but their reduction efficiency and longevity have been far less than that of the competing ammonia-based SCR systems, such as urea [3]. A catalyst has been developed to significantly reduce NOx emissions, approaching 60% with ULSD and exceeding 95% with E85. Both thermal and sulfur aging are applied, as well as on-engine aging, illustrating resilient performance to accommodate necessary life requirements. A robust system is developed to introduce both ULSD from the vehicle's tank as well as E85 (up to 85% ethanol with the balance being gasoline) from a moderately sized supplemental tank, enabling extended mileage service intervals to replenish the reductant, as compared with urea, particularly when coupled with an engine-out based NOx reduction technology, such as EGR.

Stringent global emissions legislation demands effective NOx reduction strategies, particularly for the aftertreatment, and current typical liquid urea SCR systems achieve efficiencies greater than 90% [1]. However, with such high-performing systems comes the trade-off of requiring a tank of reductant (urea water solution) to be filled regularly, usually as soon as the fuel fillings or as far as oil changes. Advantages of solid reductants, particularly ammonium carbamate, include greater ammonia densities, enabling the reductant refill interval to be extended several multiples versus a given reductant volume of urea, or diesel exhaust fluid (DEF) [2]. An additional advantage is direct gaseous ammonia dosing, enabling reductant injection at lower exhaust temperatures to widen its operational coverage achieving greater emissions reduction potential [3], as well as eliminating deposits, reducing mixing lengths, and avoiding freeze/thaw risks and investments.