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An unified model with a single set of kinetic parameters has been proposed for modeling laminar flame velocities of several alkanes using detailed kinetic mechanisms automatically generated by the EXGAS software. The validations were based on recent data of the literature. The studied compounds are methane, ethane, propane, n-butane, n-pentane, n-heptane, iso-octane, and two mixtures for natural gas and surrogate gasoline fuel. Investigated conditions are the following: unburned gases temperature was varied from 300 to 600 K, pressures from 0.5 to 25 bar, and equivalence ratios range from 0.4 to 2. For the overall studied compounds, the agreement between measured and predicted laminar burning velocities is quite good.

A modeling study of benzene formation was performed in five low-pressure, rich, laminar premixed flames with acetylene, ethylene, propene, benzene and heptane as fuels. Three published detailed reaction mechanisms were tested against molecular beam mass spectrometry (MBMS) species profiles for each flame. Differences between the three mechanisms were explored with emphasis put on benzene and acetylene profiles. It results from this study that the C3H3 path plays a major role in benzene formation whereas the C4 route is negligible. Better results obtained with Kyne's mechanism can be explained by the reversibility of the C3H3 + C3H3 = C6H6 reaction.