Technical Paper
Dilution, Thermal and Chemical Effects of Carbon Dioxide on n-heptane Two-Stage Auto-Ignition Process
2016-04-05
2016-01-0756
Exhaust gas recirculation (EGR) has been proven an effective strategy for the ignition and combustion control in homogeneous charge compression ignition (HCCI) engines. Carbon dioxide (CO2), a major constituent in EGR, was found to pose a coupled effect on engine combustion: reduced intake oxygen concentration (dilution effect), increased gas heat capacity (thermal effect) and participation of CO2 in chemical reactions (chemical effect). In this paper, a numerical study using a detailed chemical kinetic model was conducted, aiming to isolate the dilution, thermal and chemical effects of CO2 on the two-stage auto-ignition process of n-heptane at engine-like pressure conditions. Four different initial temperatures were selected in this study, representing the low-temperature dominant region, the boundary between the low-temperature region and the negative temperature coefficient (NTC) region, the NTC region and the high temperature region, respectively.