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Diesel engines have been identified as contributing to more than half of the transport sectors black carbon (BC) emissions in the US. This large contribution to atmospheric BC concentrations has raised concern about source specific emission rates, including off-highway engines. The European Union has recently implemented more stringent particulate regulations in the form of particle number via the Particle Measurement Programme (PMP) methodology. The PMP method counts the non-volatile fraction of particulate matter (PM) above 23 nm and below 2.5 μm via a condensation particle counter. This study evaluates a surrogate black carbon method which uses the PMP particle count method with a correlation factor to the BC fraction. The transient capable Magee Scientific Aethalometer (AE-33) 880 nm wavelength channel was used to determine the BC fraction.

More stringent emission requirements for nonroad diesel engines both in the U.S. and Europe have spurred the development of engines and exhaust aftertreatment technologies. In this study, one such system consisting of a diesel oxidation catalyst, zeolite-based selective catalytic reduction catalyst, and an ammonia oxidation catalyst was evaluated using both nonroad transient and steady-state cycles in order to understand the emission characteristics of this configuration. Criteria pollutants were analyzed and particular attention was given to organic compound and NO2 emissions since both of these could be significantly affected by the absence of a diesel particulate filter that typically helps reduce semi-volatile and particle-phase organics and consumes NO2 via passive soot oxidation. Results are then presented on a detailed speciation of organic emissions including alkanes, cycloalkanes, aromatics, polycyclic aromatic hydrocarbons and their derivatives, and hopanes and steranes.

Titanium dioxide supported vanadium oxide catalysts have been successfully utilized for the selective catalytic reduction (SCR) of nitrogen oxides emitted from both stationary and mobile sources. Because of their cost and performance advantages in certain applications, vanadium-based SCR catalysts are now also being considered for integration into some U.S. Tier IV off-highway aftertreatment systems. However, concern exists that toxic vanadium compounds, such as vanadium pentoxide, could be released from these catalysts as a result of mechanical attrition or high temperature volatility. An experimental study has been conducted to compare various techniques for measuring the release of particle and vapor-phase vanadium from SCR catalysts. Previous research has utilized a powder reactor-based method to measure the vapor-phase release of vanadium, but there are inherent limitations to this technique.

With the on- and off-road diesel engine emission regulations getting more stringent across the world, diesel aftertreatment systems are expected to deliver outstanding performance and reliability. These objectives should be met by fulfilling tight packaging constraints and incurring only modest material and testing costs. A major strategy for meeting these often conflicting requirements is the effective use of simulation tools such as computational fluid dynamics (CFD) in system design and performance evaluation. Prerequisites for using this CFD analysis-led-design approach, however, are knowledge of the confidence level of the predictions and knowledge of the appropriate transfer functions that establish the relationships between the measured performance parameters and model predictions. The primary aim of the present work is to develop statistically and physically relevant measures that assess the uniformity of flow in aftertreatment systems.