Journal Article
Optical and Numerical Investigations on the Mechanisms of Deposit Formation in SCR Systems
2014-04-01
2014-01-1563
Long-term reliability is one of the major requirements for the operation of automotive exhaust aftertreatment systems based on selective catalytic reduction (SCR). For an efficient reduction of nitrogen oxides in the SCR catalyst it is desirable that the thermolysis of the injected urea water solution (UWS) is completed within the mixing section of the exhaust system. Urea might undergo a number of secondary reactions leading to the formation of solid deposits on system walls. A deeper understanding of the mechanisms and influence factors is a basic requirement to prevent and predict undesired decomposition products. This paper outlines the mechanisms of UWS transport and deposition on a typical mixing element geometry. The conditions leading to deposit formation were investigated based on optical and temperature measurements in a box with optical access. A good correlation with the deposit location observed at the close-to-series exhaust system was found.