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Dimethyl ether (DME) is an alternative to diesel fuel for use in compression-ignition engines with modified fuel systems and offers potential advantages of efficiency improvements and emission reductions. DME can be produced from natural gas (NG) or from renewable feedstocks such as landfill gas (LFG) or renewable natural gas from manure waste streams (MANR) or any other biomass. This study investigates the well-to-wheels (WTW) energy use and emissions of five DME production pathways as compared with those of petroleum gasoline and diesel using the Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET®) model developed at Argonne National Laboratory (ANL).

When using dimethyl ether (DME) to fuel diesel engines at high load and speed, applying high amounts of exhaust gas recirculation (EGR) to limit NOX emissions, carbon monoxide (CO) emissions are generally high. To address this issue, the combustion and emission processes in such engines were analyzed with the three-dimensional CFD KIVA3V code. The combustion sub-mechanism (76 species and 375 reactions) was validated by comparing simulated ignition delays and flame velocities to reference data under diesel-like and atmospheric conditions, respectively. In addition, simulated and experimentally determined rate of heat release (RoHR) curves and emission data were compared for a heavy-duty single-cylinder DME engine (displaced volume, 2.02 liters) with DME-adapted piston and nozzle geometries. The simulated RoHR curves captured the main features of the experimentally measured curves, but deviated in the premixed (higher peak) and late combustion phases (too high).

DME was tested in a heavy duty diesel engine and in an optically accessible high-temperature and pressure spray chamber in order to investigate and understand the effect of nozzle parameters on emissions, combustion and fuel spray concentration. The engine study clearly showed that smaller nozzle orifices were advantageous from combustion, efficiency and emissions considerations. Heat release analysis and fuel concentration images indicate that smaller orifices result in higher mixing rate between fuel and air due to reductions in the turbulence length scale, which reduce both the magnitude of fuel-rich regions and the steepness of fuel gradients in the spray, which enable more fuel to burn and thereby shorten the combustion duration.

In the study reported here the combustion and emission characteristics of a heavy duty six-cylinder diesel engine fuelled with dimethyl ether (DME) of chemical grade and DME with small and varying amounts of methanol and/or water were experimentally investigated. In addition, the size distribution of emitted particles and selected unregulated emissions were sampled. Methanol and water additions had a very limited effect on emissions, but affected the combustion processes in a way that accentuated the premixed combustion and thus caused more energy to be released early in the cycle. At high load, however, the effect was reversed, due to the lack of distinct premixed combustion. The results confirm that DME combustion does not generate any accumulation mode particles. The particles that are detected are smaller than the soot size range and do not occur in greater numbers than those from a diesel engine in the corresponding size range.

Combustion characteristics of dimethyl ether, DME, have been investigated experimentally, in a heavy duty single cylinder engine equipped with an adapted common rail fuel injection system, and the effects of varying injection timing, rail pressure and exhaust gas recirculation on the combustion and emission parameters. The results show that DME combustion does not produce soot and with the use of exhaust gas recirculation NOX emissions can also be reduced to very low levels. However, high injection pressure and/or a DME adopted combustion system is required to improve the mixing process and thus reduce the combustion duration and carbon monoxide emissions.