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Automotive SCR systems are dimensioned to reduce NOx efficiently in normal driving conditions. In markets such as North America and Europe, extreme winter conditions are common over a period of many weeks where temperatures are usually below DEF (Diesel Exhaust Fluid) freezing temperatures at −11°C (12°F). In previous studies and applications, DEF was heated in the tank in a dedicated pot or alternatively by a standardized central heater. Due to the local character of these heating solutions, it was not possible to thaw the full tank volume. The objective of this study is to demonstrate how to significantly improve performance of the SCR system in cold weather conditions for passenger car, light commercial vehicles and SUV applications. The performance improvement is demonstrated by sustainability testing showing how much of the full tank content can be thawed and made available for injection in the exhaust system.