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The long-term weathering behavior of three different 3D printable, non-stabilized, UV cure resin formulations (A and B with thiol-ene base, and C with acrylate chemistry) was studied using tensile testing, nano-indentation, and photoacoustic infrared (FTIR-PAS) spectroscopy. To this end, type I tensile bars were printed from each resin system using a 3D printer, and were post UV-cured under a broad spectrum source. Systems A and C showed a similar trend after weathering. They first experienced an increase in modulus and tensile strength, due to additional crosslinking of the residual unreacted species. This increase in mechanical properties was followed by a drop in modulus, tensile strength, and percent elongation, due to the over-crosslinking and consequent embrittlement. System B, however, showed remarkable retention of the mechanical properties before/after weathering.

Automakers have the opportunity to utilize bio-based composite materials to lightweight cars while replacing conventional, nonrenewable resource materials. In this study, Life Cycle Assessment (LCA) is used to understand the potential benefits and tradeoffs associated with the implementation of bio-based composite materials in automotive component production. This cradle-to-grave approach quantifies the fiber and resin production as well as material processing, use, and end of life for both a conventional glass-reinforced polypropylene component as well as a cellulose-reinforced polypropylene component. The comparison is calculated for an exterior component on a high performance vehicle. The life cycle primary energy consumption and global warming potential (GWP) are evaluated. Reduced GWP associated with the alternative component are due to the use of biomass as process energy and carbon sequestration, in addition to the alternative material component's lightweighting effect.