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In order to reduce engine out CO2 emissions it is a main subject to find new alternative fuels out of renewable sources. For this reason in this paper a blend out of 1-octanol and di-n-butylether and pure di-n-butylether are investigated in comparison to n-heptane as diesel-like fuel. The alternative fuels have a different combustion behavior particularly concerning important combustion parameters like ignition delay and mixture formation. Especially the formation of pollutants like nitrogen oxides in the combustion of alternative fuels is of global interest. The knowledge of the combustion behavior is important to design new engine geometries or implement a new calibration of the engine. In previous measurements in a single cylinder engine it was found out that both alternative fuels form nearly no soot emissions. For this reason now NOx is investigated optically to avoid the traditional soot NOx trade-off in diesel combustion.

Maintaining low NOx emissions over the operating range of diesel engines continues to be a major issue. However, optical measurements of nitric oxide (NO) are lacking particularly in the core of diesel jets, i.e. in the region of premixed combustion close to the spray axis. This is basically caused by severe attenuation of both the laser light and fluorescent emission in laser-induced fluorescence (LIF) applications. Light extinction is reduced by keeping absorption path lengths relatively short in this work, by investigating diesel jets in a combustion vessel instead of an engine. Furthermore, the NO-detection threshold is improved by conducting 1-d line measurements instead of 2-d imaging. The NO-LIF data are corrected for light attenuation by combined LIF and spontaneous Raman scattering. The quantified maximum light attenuation is significantly lower than in comparable previous works, and its wavelength dependence is surprisingly weak.

With increasing interest in new biofuel candidates, 1-octanol and di-n-butylether (DNBE) were presented in recent studies. Although these molecular species are isomers, their properties are substantially different. In contrast to DNBE, 1-octanol is almost a gasoline-type fuel in terms of its auto-ignition quality. Thus, there are problems associated with engine start-up for neat 1-octanol. In order to find a suitable glow-plug position, mixture formation is studied in the cylinder under almost idle operating conditions in the present work. This is conducted by planar laser-induced fluorescence in a high-speed direct-injection optical diesel engine. The investigated C8-oxygenates are also significantly different in terms of their evaporation characteristics. Thus, in-cylinder mixture formation of these two species is compared in this work, allowing conclusions on combustion behavior and exhaust emissions.

Fuel consumption and NOx emissions of gasoline engines at part load can be significantly reduced by Controlled Auto-Ignition combustion concepts. However, the range of Gasoline Controlled Auto-Ignition (GCAI) operation is still limited by lacking combustion stability at low load and by high pressure-rise rates toward higher loads. Previous investigations indicate that the auto-ignition process is particularly determined by the thermodynamic state of the charge and by stratification effects of residual gas, temperature, and air-fuel ratio. However, little experimental data exist on the direct influence of mixture stratification on local ignition and heat-release rate (HRR) in direct-injection (DI) GCAI engines, because it is challenging to measure all the relevant charge and combustion parameters quasi-simultaneously with sufficient spatial/temporal resolution and precision.

Pilot injection (PI) during the negative-valve-overlap (NVO) period is one method to improve control of combustion in gasoline controlled auto-ignition engines. This is generally attributed to both chemical and thermal effects. However, there are little experimental data on active species formed by the combusting PI and their effect on main combustion in real engines. Thus, it is the objective of the current study to apply and assess optical in-cylinder diagnostics for these species. Firstly, the occurrence and nature of combustion during the NVO period is investigated by spectrally-resolved multi-species flame luminescence measurements. OH*, CH*, HCO*, CO-continuum chemiluminescence, and soot luminosity are recorded. Secondly, spectrally-, spatially-, and cycle-resolved laser-induced fluorescence measurements of formaldehyde are conducted. It is attempted to find a cycle-resolved measure of the chemical effect of PI.

Multiple-injection strategies are widely used in DI diesel engines. However, the interaction of the injection pulses is not yet fully understood. In this work, a split injection into a combustion vessel is studied by multiple optical imaging diagnostics. The vessel provides quiescent high-temperature, high-pressure ambient conditions. A common-rail injector which is equipped with a three-hole nozzle is used. The spray is visualized by Mie scattering. First and second stage of ignition are probed by formaldehyde laser-induced fluorescence (LIF) and OH* chemiluminescence imaging, respectively. In addition formation of soot is characterized by both laser-induced incandescence (LII) and natural luminosity imaging, showing that low-sooting conditions are established. These qualitative diagnostics yield ensemble-averaged, two-dimensional, time-resolved distributions of the corresponding quantities.

Downsizing of highly-boosted spark-ignition (SI) engines is limited by pre-ignition, which may lead to extremely strong knocking and severe engine damage. Unfortunately, the concerning mechanisms are generally not yet fully understood, although several possible reasons have been suggested in previous research. The primary objective of the present paper is to investigate the influence of molecular bio-fuel structure on the locations of pre-ignition in a realistic, highly-charged SI engine at low speed by state-of-the-art optical measurements. The latter are conducted by using a high-sensitivity UV endoscope and an intensified high-speed camera. Two recently tested bio-fuels, namely tetrahydro-2-methylfuran (2-MTHF) and 2-methylfuran (2-MF), are investigated. Compared to conventional fuels, they have potential advantages in the well-to-tank balance. In addition, both neat ethanol and conventional gasoline are used as fuels.

It is the objective of this work to characterize mixture formation in the sprays emanating from Multi-Layer (ML) nozzles under approximately engine-like conditions by quantitative, spatially, and temporally resolved fuel-air ratio and temperature measurements. ML nozzles are cluster nozzles which have more than one circle of orifices. They were introduced previously, in order to overcome the limitations of conventional nozzles. In particular, the ML design yields the potential of variable spray interaction, so that mixture formation could be controlled according to the operating condition. In general, it was also a primary aim of the cluster-nozzle concepts to combine the enhanced atomization and pre-mixing of small nozzle holes with the longer spray penetration lengths of large holes. The applied diagnostic, which is based on 1d spontaneous Raman scattering, yields the quantitative stoichiometric ratio and the temperature in the vapor phase.

Tailor-made multi-component fuels are currently being developed for advanced Diesel engines. Accordingly, there is renewed interest in the detailed evaporation characteristics of such multi-component fuels, in particular because soot formation in reacting Diesel sprays generally depends on the mixture formation upstream of the lift-off location. It is also well established that fuel components with different volatility are generally not coevaporative due to fractional distillation in the mixture formation process of spark-ignition engines, but it is not clear if this holds for Diesel-like sprays, in which evaporation and mixing are expected to be more rapid. Unfortunately, little work has been done in this field, and some of the previous results appear to be contradictory. This paper presents a new laser diagnostic approach, which yields the vapor-phase concentrations of two fuel components simultaneously in Diesel-like sprays.

The finite nature and instability of fossil fuel supply has led to an increasing and enduring investigation demand of alternative and regenerative fuels. An investigation program is carried out to explore the potential of tailor made fuels to reduce engine-out emissions while maintaining engine efficiency and an acceptable noise level. In this paper, fundamental results of the Diesel engine relevant combustion are presented. To enable optimum engine performance a range of different reference fuels have been investigated. The fundamental effects of different physical and chemical properties on emission formation and engine performance are investigated using a thermodynamic diesel single cylinder research engine and an optically-accessible combustion vessel. Depending on the chain length and molecular structure, fuel compounds vary in cetane number, boiling temperature etc. Therefore, different hydrocarbons including n-heptane, n-dodecane, and l-decanol were investigated.

One of the basic topics in the design of new injection systems for DI Diesel engines is to decrease the soot emissions. A promising approach to minimize soot production are nozzles with clustered holes. A basic idea of the Cluster Configuration (CC) nozzles is to prevent a fuel rich area in the center of the flame where most of the soot is produced, and to minimize the overall soot formation in this way. For this purpose each hole of a standard nozzle is replaced by two smaller holes. The diameter of the smaller holes is chosen so that the flow rate of all nozzles should be equal. The basic strategy of the cluster nozzles is to provide a better primary break up and therefore a better mixture formation caused by the smaller nozzle holes, but a comparable penetration length of the vapor phase due to merging of the sprays. Three possible arrangements of the clustered holes are investigated in this study. Both the cluster angle and the orientation to the injector axis are varied.

The droplet velocity is an important parameter for breakup, evaporation, and combustion of Diesel sprays, but it is very difficult to measure it by widely used laser diagnostic techniques like PDA, PIV and LCV under realistic high-pressure and high-temperature conditions. This is basically caused by laser beam steering and multiple scattering of light due to very high droplet densities, in particular close to the nozzle. It was demonstrated recently, that these problems can be greatly reduced by the laser flow tagging (LFT) technique. For this purpose, the model fuel is doped with a phosphorescent tracer. A number of droplet groups within the spray are tagged by illuminating them with focused beams of a pulsed laser, and their velocities are measured by recording the phosphorescence twice after each laser pulse using a double-frame ICCD.

Mixture formation plays an important role for combustion and pollution formation in Diesel sprays. In particular air/fuel ratio (AFR) and temperature of the mixture short before ignition are crucial for these processes. Thus, these two quantities were measured quantitatively using 1-d spontaneous Raman scattering in this work. In addition, 1-d and 2-d Mie scattering was applied to visualize the distribution of the fuel droplets. 1-d and 2-d laser induced fluorescence (LIF) was also used to measure oxygen and fuel in a qualitative way in this work. The common rail Diesel injector was installed in a combustion vessel, in order to provide nearly quiescent high-pressure and high-temperature conditions. N-decane was used as the fuel, because it is a commonly used model fuel for standard Diesel fuel. It was doped with three different tracers with different boiling points in consecutive experiments in the case of 2-d LIF measurements.

The influence of different fuels and injection pressures on the flame lift-off length (LOL), as well as the combustion structure under quiescent conditions in a heated high-pressure vessel were experimentally investigated using OH chemiluminescence measurements. This data was used to validate the newly developed G-equation coupled with MRIF (G-MRIF) model, which was designed to describe the lifted Diesel combustion process. The achieved results are very promising and could be used as a tool to apply this combustion mode into Diesel engines. Furthermore these measurements were used to validate the approach of a new combustion model, which was developed using former OH chemiluminescence measurements by the authors. Based on this approach the LOL is mainly determined by auto-ignition and therefore highly dependent on the cetane number. This model is presented in more detail within this work.

Cyclic fluctuations of the in-cylinder processes in a Direct Injection Spark Ignition (DISI) engine may strongly affect the engine operation causing misfires or variations in the indicated mean effective pressure (imep). Particularly misfires prevent compliance with current or future exhaust emission legislations. Nevertheless, the origin of cyclic fluctuations is not well understood since fluctuations of in-cylinder air flow, fuel injection and wall interaction have to be considered. This paper focusses on a detailed experimental analysis of the origin of cyclic fluctuations in a DISI engine with an air guided combustion process by means of advanced Laser Induced Exciplex Fluorescence (LIEF) measurements. It reveals that cycle-to-cycle variations primarily originate from the air/fuel ratio at the spark plug.