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The development and calibration of exhaust aftertreatment (EAT) systems for the most diverse applications of diesel powertrain concepts requires EAT models, capable of performing concept analysis as well as control and OBD system development and calibration. On the concept side, the choice of an application-specific EAT layout from a wide technology selection is driven by a number of requirements and constraints. These include statutory requirements regarding emissions of criteria pollutants and greenhouse gases (GHG), technical constraints such as engine-out emissions and packaging, as well as economic parameters such as fuel consumption, and EAT system and system development costs. Fast and efficient execution of the analysis and multi-criteria system optimization can be done by integrating the detailed EAT models into a total system simulation.

A physico-chemical model of a Cu-zeolite SCR/DPF-system involving NH₃ storage and SCR reactions as well as soot oxidation reactions with NO₂ has been developed and validated based on fundamental experimental investigations on synthetic gas test bench. The goal of the work was the quantitative modeling of NOx and NH₃ tailpipe emissions in transient test cycles in order to use the model for concept design analysis and the development of control strategies. Another focus was put on the impact of soot on SCR/DPF systems. In temperature-programmed desorption experiments, soot-loaded SCR/DPF filters showed a higher NH₃ storage capacity compared to soot-free samples. The measured effect was small, but could affect the NH₃ slip in vehicle applications. A bimodal desorption characteristic was measured for different adsorption temperatures and heating rates.

One of the main challenges in developing cost-effective diesel particulate filters is to guarantee a thermally safe regeneration under all possible conditions on the road. Uncontrolled regenerations occur when the soot reaction rate is so high that the cooling effect of the incoming exhaust gas is insufficient to keep the temperature below the required limit for material integrity. These conditions occur when the engine switches to idle while the filter is already hot enough to initiate soot oxidation, typically following engine operation at high torque and speed or active filter regeneration. The purpose of this work is to investigate engine management techniques to reduce the reaction rate during typical failure mode regenerations. A purely experimental investigation faces many difficulties, especially regarding measurement accuracy, repeatability in filter soot loading, and repeatability in the regeneration protocol.