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Ammonia has attracted the attention of a growing number of researchers in recent years. However, some properties of ammonia (e.g., low laminar burning velocity, high ignition energy, etc.) inhibit its direct application in engines. Several routes have been proposed to overcome these problems, such as oxygen enrichment, partial fuel cracking strategy and co-combustion with more reactive fuels. Improving the reactivity of ammonia from the oxidizer side is also practical. Ozone is a highly reactive oxidizer which can be easily and rapidly generated through electrical plasma and is an effective promoter applicable for a variety of fuels. The dissociation reaction of ozone increases the concentration of reactive radicals and promotes chain-propagating reactions. Thus, obtaining accurate rate constants of reactions related to ozone is necessary, especially at elevated to high pressure range which is closer to engine-relevant conditions.

To achieve higher efficiencies and lower emissions, dual-fuel strategies have arisen as advanced engine technologies. In order to fully utilize engine fuels, understanding the combustion chemistry is urgently required. However, due to computation limitations, detailed kinetic models cannot be used in numerical engine simulations. As an alternative, approaches for developing reduced reaction mechanisms have been proposed. Nevertheless, existing simplified methods neglecting the real engine combustion processes, which is the ultimate goal of reduced mechanism. In this study, we propose a novel simplified approach based on fuel reactivity. The high-reactivity fuel undergoes pyrolysis first, followed by the pyrolysis and oxidation of the low-reactivity fuel. Therefore, the simplified mechanism consists of highly lumped reactions of high-reactivity fuel, radical reactions of low-reactivity fuel and C0-C2 core mechanisms.

Euro VI emission standards have set a very strict limitation on particulate matter emissions of Gasoline Direct Injection (GDI) engine. It is difficult for GDI engine to meet the Euro VI PN regulation (6×1011#/km) without a series of complicated after-treatment devices such as Gasoline Particulate Filter (GPF). Previous research shows that GDI vehicles under cold start condition account for more than 50% of both particle number and mass emissions during the entire NEDC driving cycle. Dual Injection Gasoline engine is based on the GDI engine by adding a set of port fuel injection system. The good mixing characteristics of the port fuel injection system can help to reduce the particulate matter emissions of the GDI engine during the cold start condition.

European standards have set stringent PN (particle number) regulation (6×1011 #/km) for gasoline direct injection (GDI) engine, posing a great challenge for the particulate emission control of GDI engines. Dual-injection, which combines direct-injection (DI) with port-fuel-injection (PFI), is an effective approach to reduce particle emissions of GDI engine while maintaining good efficiency and power output. In order to investigate the PN emission characteristics under different dual-injection strategies, a DMS500 fast particle spectrometer was employed to characterize the effects of injection strategies on particulates emissions from a dual-injection gasoline engine. In this study, the injection strategies include injection timing, injection ratio and injection pressure of direct-injection.

Ignition quality tester (IQT) is a standard experimental device to determine ignition delay time of liquid fuels in a controlled environment in the absence of gas exchange. The process involves fuel injection, spray breakup, evaporation and mixing, which is followed by auto-ignition. In this study, three-dimensional computational fluid dynamics (CFD) is used for prediction of auto-ignition characteristics of diethyl ether (DEE) and ethanol. In particular, the sensitivity of the ignition behavior to different injection rate profiles is investigated. Fluctuant rate profile derived from needle lift data from experiments performs better than square rate profile in ignition delay predictions. DEE, when used with fluctuant injection rate profile resulted in faster ignition, while for ethanol the situation was reversed. The contrasting results are attributed to the difference in local mixing.

In-cylinder thermochemical fuel reforming (TFR) in spark ignition natural gas engine was developed to reveal that thermochemical fuel reforming could increase H2 and CO concentration in reformed gas, leading to an increase of thermal efficiency and engine performance. Moreover, ethanol enrichment has been proved to have great potential to optimize TFR performance. In order to explain TFR phenomenon chemically, methane oxidation experiments were conducted in a laminar flow reactor with addition of ethanol and methanol at equivalent ratios of 1.5, 1.7, 1.9 and 2.1 from 948K to 1098K at atmospheric pressure. Experimental results showed that methanol have great ability to facilitate the oxidation of methane than that of ethanol. Meanwhile, the degree of methane conversion became more significantly as the equivalent ratio increased. Kinetic analysis of oxidation of methane with alcohol enrichment in a plug flow model was also conducted in this study.

Recently, the shortage of fossil resources contributes to strict regulations of environmental protection. The research on the high efficiency and low emission of engines becomes an important direction all over the world. Technologies like high injection pressure, high levels of supercharging and higher levels of back pressure have come into application. Increasing the injection pressure and average cylinder pressure results in that parts of the spray can experience transcritical and supercritical regimes. In this paper, we established a surrogate fuel composed of n-Hexadecane, HMN and 1-Metylnaphthalene, to analyze the injection and atomization of diesel surrogate fuel with large eddy simulation (LES) in a cubic calculation region with high temperature and high pressure environment. The injection pressure was fixed to 150MPa, and the 900-K temperature and the 6-MPa pressure represented the ambient condition in constant volume vessel which is supercritical with respect to No.2 diesel.

Combustion instability often occurs inside the combustion chamber of aero engine. Fuel atomization and evaporation, one of the controlling processes of combustion rate, is an important mechanism of the combustion instability. To tackle combustion instability, it challenges a deep understanding of the underlying mechanism of fuel atomization and evaporation. In this paper, acoustic field was established to simulate the pressure oscillation. Transient spray images of ethanol and kerosene were recorded using high-speed camera. The obtained images were processed by MATLAB to extract and analyze the related data. Spatial fuel atomization characteristics was analytically examined by multi-threshold image method to analyze the effect of the high frequency acoustic field on the fuel break-up and disintegration. The results show that the half spray cone angle on the side with speaker is suppressed by the presence of the imposed acoustic field compared with the case without speaker.

In the present study a novel surrogate model for biodiesel including methyl decanoate (MD) and methyl crotonate (MC) was proposed and validated. In the binary mixture of surrogate fuel, MD was chosen to represent saturated methyl esters, which exhibited great low-temperature reactivity with typical negative temperature-coefficient (NTC) behavior and MC represented unsaturated components in real biodiesel, which was mainly responsible for soot formation and evolution. The proportion of MD and MC was determined by matching the characteristics such as derived cetane number (DCN), molecular weight (MW), atom number, H/C ratio and unsaturated degree. All of the criterions were calculated by the least square principles and the calculated surrogate of biodiesel was comprised of 92% MD and 8% MC in mole fraction. Furthermore, detailed kinetic model of the surrogate fuel was constructed and developed with modifications, which was composed of 2918 species and 9164 reactions.

Biodiesel is a potential alternative fuel which can meet the growing need for sustainable energy. Partially premixed compression ignition (PPCI) is an important low-temperature combustion strategy to reduce NOx and soot emission of diesel engines. To investigate partial premixing impact on particle formation in flames of biodiesel or biodiesel surrogates, an experimental study was performed to compare the soot morphology and nanostructure evolution in laminar co-flow methyl decanoate non-premixed flame (NPF) and partially premixed flame (PPF). The thermophoretic sampling technique was used to capture particles along flame centerlines. Soot morphology information and volume fraction were obtained from TEM analysis and nanostructure features were evaluated by HR-TEM. With primary equivalence ratio of 19, gas temperature of PPF is higher along flame centerline compared with NPF. The results show an initially stronger sooting tendency in PPF at lower positions.

In this paper, an experimental study has been conducted to study the effects of iso-alkanes blending in diesel on combustion and emission characters based on a modified single cylinder diesel engine. Iso-octane, iso-dodecane and 2,2,4,4,6,8,8-heptamethylnonane (HMN) were chosen as test iso-alkanes. The direct injection timing was kept at 7 oCA BTDC. The injection pressure was maintained at 120 MPa. The study found that iso-alkanes had strong effects on the heat release phase under low load. The effects were weakened gradually with the increase of loads. The peak value of heat release curves and the maximum pressure rising rate gradually increased with the increase of loads. Blending iso-alkanes resulted in the increase of CO emissions and decrease of HC emissions. NOx emissions also decrease under low loads. Under high loads, blending iso-alkanes reduced the soot emissions significantly.

In-cylinder thermochemical fuel reforming (TFR), which involves running one cylinder rich of stoichiometric and routing its entire exhaust back into the intake manifold, is an attractive method for improving engine performances. Compared with other hydrocarbon fuels, the chemical structure of methane is more stable owing to much shorter carbon chain. As ethanol contains hydroxyl in chemical structure, it potentially generates OH radical during the combustion. Therefore, adding ethanol into natural gas (NG) might help the thermochemical reforming process in engine cylinder. This paper focused on researching the effects of ethanol-NG combined in-cylinder TFR on engine performances, before which the effect of NG in-cylinder TFR was examined in detail. Cylinder #4 (TFR cylinder) was running rich and its cooled exhaust was coupled to the intake manifold of a four-cylinder engine during the experiments.

Exhaust gas recirculation (EGR) has been proven an effective strategy for the ignition and combustion control in homogeneous charge compression ignition (HCCI) engines. Carbon dioxide (CO2), a major constituent in EGR, was found to pose a coupled effect on engine combustion: reduced intake oxygen concentration (dilution effect), increased gas heat capacity (thermal effect) and participation of CO2 in chemical reactions (chemical effect). In this paper, a numerical study using a detailed chemical kinetic model was conducted, aiming to isolate the dilution, thermal and chemical effects of CO2 on the two-stage auto-ignition process of n-heptane at engine-like pressure conditions. Four different initial temperatures were selected in this study, representing the low-temperature dominant region, the boundary between the low-temperature region and the negative temperature coefficient (NTC) region, the NTC region and the high temperature region, respectively.

In order to quantitatively investigate the macroscopic characteristics of flash-boiling atomization, the spray injected through a plain-orifice nozzle under atmospheric conditions was directly imaged and analyzed by the multi-threshold algorithm. The spray images were acquired at various times after the start of actuation using a high-speed visualization system. The light intensity level of images implies the local relative mass concentration of droplets in the spray. Transient contour plots of spray images at various thresholds were analyzed and compared with turbulent round jets of diesel. A new term, transient continuous cone angle, was defined to characterize the flash-boiling spray. The relative mass concentration distributions and continuous cone angles of the sprays during the start, development and end periods of the atomization were discussed for two different sprays.

Because of its cleanness and renewability, biodiesel has a great potential as the alternative of diesel fuel to confront with the increasing energy crisis and environment pollution. In this study, diesel oxidation catalyst (DOC) was used to reduce the typical regulated emission and particulate emission. The combined method of fuel design concept with diesel oxidation catalyst was applied in this study. DOC with Pt catalyst was equipped in the engine test bench in this study. The effects of DOC on diesel engine particulate emission fueled with Euro V diesel fuel, biodiesel and ethanol-biodiesel blends were investigated in this study. It was found that DOC seemed have no effects on NOx emission, while it could improve the oxidation reaction from NO to NO2. In the section of particulate emission, DOC could reduce the particulate mass and number concentration, especially in the range of smaller diameter particles. The SOF could be reduced effectively with DOC.

Engine lubricating oil perform functions including wear reduction, friction reduction, piston cooling, corrosion prevention, cleaning pistons, preventing leakage and serving as a hydraulic media. Oil aeration is the entrapment of air into engine oil during operation. Aeration would affect oil density, viscosity and its sound velocity, with a detriment to such properties as lubricity, cooling and lubricating temperature, possibly resulting in worse engine working environment. In this paper, a new volume method with temperature compensation is introduced and proved to be indispensable. The measurement of oil aeration rate is performed with the main oil gallery of a four cylinder, turbocharged, high-speed diesel engine under different operating conditions. The temperature compensation is carried out for the measured oil aeration rate and the compensation effect evaluated. The variation of oil aeration rate with time after oil leaving the main oil gallery is also presented.

An experimental study was conducted on the combustion and emissions characteristics of duel fuel sequential combustion (DFSC) mode on a single-cylinder engine, applying port injection of n-heptane combined with in-cylinder direct injection of commercial gasoline, ethanol and n-butyl alcohol, respectively. Three-stage combustion, which consists of low- and high-temperature combustion of premixed n-heptane and high temperature combustion of directly injected gasoline-like fuels were observed. The effects of the premixed ratio and overall heating values per cycle on the combustion characteristics and emissions were investigated. The experimental results show that: with the increasing of premixed ratio and overall heating values per-cycle, the ignition timing of the directly injected fuels advances and the maximum pressure and maximum mass-averaged temperature increase.

The aim of this study is to evaluate the land requirement, energy consumption and GHG (greenhouse gases) emissions of microalgal biodiesel (M-BD) and Jatropha curcas seeds (J-BD) based biodiesel from the perspective of life cycle assessment (LCA). Mass and energy balance was used through the whole LCA calculation for each process. Two types of biodiesel (100% biodiesel: BD100, and 20% blends of biodiesel: BD20) were assumed to be combusted in the suitable diesel engine. Displacement method was adopted to measure the co-products credits. The results showed that the land requirement of producing 1 kg biodiesel from microalgae was about 1/31 of that from Jatropha curcas seeds. The well to pump (WTP) stage for microalgal biodiesel had higher fossil energy requirement but lower petroleum energy consumption and GHG emissions compared to Jatropha curcas and conventional diesel (CD). The WTP energy efficiency for J-BD100 and M-BD 100 were 26% and 17.4%, respectively.

This study provides a life cycle assessment (LCA) of plug-in hybrid electric vehicle (PHEV) fuel cycle. PHEVs recharging from the average electricity generation mix of China provide 16%-29% fossil energy consumption reduction, 39%-52% petroleum energy consumption reduction and 5%-26% greenhouse gas (GHG) emissions reduction compared with conventional gasoline vehicle. The range of the results is primarily attributed to the different all electric range (AER) and PHEV types (power-split versus series designs). Impacts of electricity generation mix for battery recharging are studied by six different interprovincial power grids, one prediction electricity scenario, and the average electricity generation mix of China. Fossil energy consumption and GHG emissions of PHEVs recharging from six different interprovincial power grids show 9%-24% and 12%-29% differences respectively.

This article investigates the basic combustion parameters including start of ignition, combustion duration, and CO, UHC, and NOx emissions of HCCI combustion engines fueled with primary reference fuels and their mixtures. A single-cylinder HCCI combustion engine, which was converted from a four-cylinder high-speed diesel engine, was used to the tests. Two primary reference fuels, n-heptane and iso-octane, and their mixtures including RON25, RON50, RON75, and RON90 were evaluated. In addition, the effects of cooled EGR on the HCCI combustion and emissions were also studied. The experimental results shown that, in the first-stage combustion, with the increase of the research octane number, the start of ignition retards, the combustion duration shortens, and the pressure rising and the temperature rising during the first-stage combustion decrease. Furthermore, the cumulative heat release in the first stage is strongly dependent on the concentration of n-heptane in the mixtures.