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Under the U.S. Environmental Protection Agency's (EPA's) Heavy-Duty In-Use Testing (HDIUT) program, emission of non-methane hydrocarbons (NMHC), carbon monoxide (CO), and oxides of nitrogen (NOx) have been regulated using Portable Emissions Measurement Systems (PEMS) during in-use field operation for heavy-duty on-highway diesel engines with 2007 or later model year designations. As directed by the EPA, the Engine Manufacturers Association (EMA), and the California Air Resources Board (CARB), additive emission measurement accuracy margins (measurement allowances) were experimentally determined for HDIUT to account for the measurement differences between laboratory testing with laboratory grade equipment and in-use testing with PEMS. As part of a three-paper series, this paper summarizes the HDIUT measurement allowance program while focusing on the laboratory evaluations of the Sensors Inc. SEMTECH-DS PEMS.

Beginning in 2007, heavy-duty engine manufacturers in the U.S. have been responsible for verifying the compliance on in-use vehicles with Not-to-Exceed (NTE) standards under the Heavy-Duty In-Use Testing Program (HDIUT). This in-use testing is conducted using Portable Emission Measurement Systems (PEMS) which are installed on the vehicles to measure emissions during real-world operation. A key component of the HDIUT program is the generation of measurement allowances which account for the relative accuracy of PEMS as compared to more conventional, laboratory based measurement techniques. A program to determine these measurement allowances for gaseous emissions was jointly funded by the U.S. Environmental Protection Agency (EPA), the California Air Resources Board (CARB), and various member companies of the Engine Manufacturer's Association (EMA).

The California Air Resources Board (CARB)-funded Stage 3 Heavy-Duty Low NOX program focusses on evaluating different engine and after-treatment technologies to achieve 0.02g/bhp-hr of NOX emission over certification cycles. This paper highlights the controls architecture of the engine and after-treatment systems and discusses the effects of various strategies implemented and tested in an engine test cell over various heavy-duty drive cycles. A Cylinder De-Activation (CDA) system enabled engine was integrated with an advanced after-treatment controller and system package. Southwest Research Institute (SwRI) had implemented a model-based controller for the Selective Catalytic Reduction (SCR) system in the CARB Stage 1 Low-NOX program. The chemical kinetics for the model-based controller were further tuned and implemented in order to accurately represent the reactions for the catalysts used in this program.

The most recent 2010 emissions standards for heavy-duty engines have established a tailpipe limit of oxides of nitrogen (NOX) emissions of 0.20 g/bhp-hr. However, it is projected that even when the entire on-road fleet of heavy-duty vehicles operating in California is compliant with 2010 emission standards, the National Ambient Air Quality Standards (NAAQS) requirement for ambient particulate matter and Ozone will not be achieved without further reduction in NOX emissions. The California Air Resources Board (CARB) funded a research program to explore the feasibility of achieving 0.02 g/bhp-hr NOX emissions.

Nitrous Oxide (N₂O) is a greenhouse gas with a Global Warming Potential (GWP) of 298-310 (298-310 times more potent than carbon dioxide (CO₂)). As a result, any aftertreatment system that generates N₂O must be well understood to be used effectively. Under low temperature conditions, N₂O can be produced by Selective Catalytic Reduction (SCR) catalysts. The chemistry is reasonably well understood with N₂O formed by the thermal decomposition of ammonium nitrate. Ammonium nitrate and N₂O form in oxides of nitrogen (NOx) gas mixtures that are high in nitrogen dioxide (NO₂). This mechanism occurs at a relatively low temperature of about 200°C, and can be controlled by maintaining the nitric oxide (NO)/NO₂ ratio above 1. However, N₂O has also been observed at relatively high temperatures, in the region of 500°C.

The classical approach to prepare engine exhaust emissions control systems for evaluation and certification is to condition the fresh parts by aging the systems on an engine/dynamometer aging stand. For diesel systems this can be a very lengthy process since the estimated service life of the emissions control systems can be several hundred thousand miles. Thus full useful life aging can take thousands of engine bench aging hours, even at elevated temperatures, making aging a considerable cost and time investment. Compared to gasoline engines, diesel engines operate with very low exhaust gas temperatures. One of the major sources of catalyst deactivation is exposure to high temperature [ 1 ].

The 2007 emission standards for both light-duty and heavy-duty diesel vehicles remain a challenge. A level of about 90% NOx conversion is required to meet the standards. Technologies that have the most potential to achieve very high NOx conversion at low temperatures of diesel exhaust are lean NOx traps (LNTs) and Selective Catalytic Reduction (SCR) of NOx using aqueous urea, typically known as Urea SCR. The LNT has the advantage of requiring no new infrastructure, and does not pose any new customer compliance issues. However, Urea SCR has high and durable NOx conversion in a wider temperature window, a lower equivalent fuel penalty, and lower system cost. On a technical basis, Urea SCR has the best chance of meeting the 2007 NOx targets. This paper reviews the results of some demonstration programs for both light-and heavy-duty applications.

It is projected that even when the entire on-road fleet of heavy-duty vehicles operating in California is compliant with 2010 emission standards of 0.20 g/bhp-hr, the National Ambient Air Quality Standards (NAAQS) requirements for ambient ozone will not be met. It is expected that further reductions in NOX emissions from the heavy-duty fleet will be required to achieve compliance with the ambient ozone requirement. To study the feasibility of further reductions, the California Air Resources Board (CARB) funded a research program to demonstrate the potential to reach 0.02 g/bhp-hr NOX emissions. This paper details the work executed to achieve this goal on the heavy-duty Federal Test Procedure (FTP) with a heavy-duty natural gas engine equipped with a three-way catalyst. A Cummins ISX-12G natural gas engine was modified and coupled with an advanced catalyst system.

Research has shown that there are many factors that affect the long-term performance of nitrogen oxides (NOx) control systems used in diesel engine applications. However, if the NOx emissions can be accurately monitored, it might be possible to restore performance by making adjustments to the control systems. This paper presents results from a study that tested the durability of 25 NOx sensors exposed to heavy-duty diesel exhaust for 6,000 hours. The study, conducted by the Advanced Petroleum-Based Fuels - Diesel Emission Controls (APBF-DEC) project, tested the sensors at various locations in the exhaust stream.

A 2003 heavy-duty diesel engine (2002 emissions level) was used to test a representative biodiesel fuel as well as the methyl esters of several different fatty acids. The fuel variables included degree of saturation, the oxygen content, and carbon chain length. In addition, two pure normal paraffins with the corresponding chain lengths of two of the methyl esters were also tested to determine the impact of chain length. The dependent variables were the NOx and the particulate emissions (PM). The results indicated that the primary fuel variable affecting the emissions is the oxygen content. The emissions results showed that the highest oxygen content test fuel had the lowest emissions of both NOx and PM. As compared to the baseline diesel fuel the NOx emissions were reduced by 5 percent and the PM emissions were reduced by 83 percent.

As governmental agencies focus on low levels of the oxides of nitrogen (NOx) emissions compliance, new off-road applications are being reviewed for both regulated and unregulated emissions to understand the technological challenges and requirements for improved emissions performance. The California Air Resources Board (CARB) has declared its intention to pursue more stringent NOX standards for the off-road market. As part of this effort, CARB initiated a program to provide a detailed characterization of emissions meeting the current Tier 4 off-road standards [1]. This work focused on understanding the off-road market, establishing a current technology emissions baseline, and performing initial modeling on potential low NOx solutions. This paper discusses a part of this effort, focuses on the emissions characterization from two non-road engine platforms, and compares the emissions species from different approaches designed to meet Tier 4 emissions regulations.

As agencies continue to focus on emissions compliance, low NOX discussions have started to propagate beyond the on-highway market. Nonroad applications, which contribute to 29% of the PM emissions and 11% of the NOX emissions in California, are being reviewed to understand the technological challenges and requirements for improved emissions performance. To help facilitate a nonroad low NOX technology demonstration, information from current engine and aftertreatment technologies required a detailed assessment. The following work will discuss the emissions characterization results from two non-road engine platforms. The intention of this study was to compare the emissions species from different approaches designed to meet Tier 4 emissions regulations. The platforms reflect available technology for DPF and non-DPF aftertreatment architectures.

With the conclusion of the California Air Resources Board (CARB) Stage 1 Ultra-Low NOX (ULN) program, there continues to be a commitment for identifying potential pathways to demonstrate 0.02 g/bhp-hr NOX emissions. The Stage 1 program focused on achieving the ULN levels on the heavy-duty regulatory cycles utilizing a turbo-compound engine which required the integration of novel catalyst technologies and a supplemental heat source. While the aftertreatment configuration provided a potential solution to meet the ULN target, a complicated approach with a greenhouse gas (GHG) penalty was required to overcome challenges from low temperature exhaust. A subsequent Stage 2 program was concerned with the development of a new low load test cycle and evaluating the trade-off between GHG and tailpipe NOX on the Stage 1 ULN solution.

With the conclusion of the California Air Resources Board (CARB) Stage 1 Ultra-Low NOX program, there continues to be a commitment for identifying potential pathways to demonstrate 0.02 g/hp-hr NOX emissions. The Stage 1 program focused on achieving the Ultra-Low NOX (ULN) levels utilizing a turbo-compound (TC) engine, which required the integration of novel catalyst technologies and a supplemental heat source. While the aftertreatment configuration provided a potential solution to meet the ULN target, a complicated approach was required to overcome challenges from low temperature exhaust. The Stage 3 program leverages a different engine architecture more representative of the broader heavy-duty industry to meet the Phase 2 Greenhouse Gas (GHG) targets and to simplify the ULN aftertreatment solution. The following work will discuss the aftertreatment technology evaluation, down selection criteria, and the emission results for the candidate ULN systems

Despite considerable progress over the last several decades, California continues to face some of the most significant air quality problems in the United States. These continued issues highlight the need for further mobile source NOX reductions to help California and other areas meet ambient air quality targets mandated by the U.S. EPA. Beginning in 2014, the California Air Resources Board (CARB) launched a program aimed at demonstrating technologies that could enable heavy-duty on-highway engines to reach tailpipe NOX levels up to 90% below the current standards, which were implemented in 2010. At the same time, mandated improvements to greenhouse gas emissions (GHG) require that these NOX reductions be achieved without sacrificing fuel consumption and increasing GHG emissions.

Recent 2010 emissions standards for heavy-duty engines have established a limit of oxides of nitrogen (NOX) emissions of 0.20 g/bhp-hr. However, CARB has projected that even when the entire on-road fleet of heavy-duty vehicles operating in California is compliant with 2010 emission standards, the National Ambient Air Quality Standards (NAAQS) requirement for ambient particulate matter and Ozone will not be achieved without further reduction in NOX emissions. The California Air Resources Board (ARB) funded a research program to explore the feasibility of achieving 0.02 g/bhp-hr NOX emissions. This paper details engine and aftertreatment NOX management requirements and model based control considerations for achieving Ultra-Low NOX (ULN) levels with a heavy-duty diesel engine. Data are presented for several Advanced Technology aftertreatment solutions and the integration of these solutions with the engine calibration.

The 2010 emissions standards for heavy-duty engines have established a limit of oxides of nitrogen (NOX) emissions of 0.20 g/bhp-hr. However, the California Air Resource Board (ARB) projects that even when the entire on-road fleet of heavy-duty vehicles operating in California is compliant with 2010 emission standards, the National Ambient Air Quality Standards (NAAQS) requirement for ambient particulate matter (PM) and Ozone will not be achieved without further reduction in NOX emissions. The California Air Resources Board (CARB) funded a research program to explore the feasibility of achieving 0.02 g/bhp-hr NOX emissions.

Eco-driving algorithms enabled by Vehicle to Everything (V2X) communications in Connected and Automated Vehicles (CAVs) can improve fuel economy by generating an energy-efficient velocity trajectory for vehicles to follow in real time. Southwest Research Institute (SwRI) demonstrated a 7% reduction in energy consumption for fully loaded class 8 trucks using SwRI’s eco-driving algorithms. However, the impact of these schemes on vehicle emissions is not well understood. This paper details the effort of using data from SwRI’s on-road vehicle tests to measure and evaluate how eco-driving could impact emissions. Two engine and aftertreatment configurations were evaluated: a production system that meets current NOX standards and a system with advanced aftertreatment and engine technologies designed to meet low NOX 2031+ emissions standards.

The use of biodiesel fuels derived from vegetable oils or animal fats as a substitute for conventional petroleum fuel in diesel engines has received increased attention. This interest is based on a number of properties of biodiesel including the fact that it is produced from a renewable resource, its biodegradability, and its potential beneficial effects on exhaust emissions. As part of Tier 1 compliance requirements for EPA's Fuel Registration Program, a detailed chemical characterization of the transient exhaust emissions from three modern diesel engines was performed, both with and without an oxidation catalyst. This characterization included several forms of hydrocarbon speciation, as well as measurement of aldehydes, ketones, and alcohols. In addition, both particle-phase and semivolatile-phase PAH and nitro-PAH compounds were measured. Unregulated emissions were characterized with neat biodiesel and with a blend of biodiesel and conventional diesel fuel.

The use of biodiesel fuels derived from vegetable oils or animal fats as a substitute for conventional petroleum fuel in diesel engines has received increased attention. This interest is based on a number of properties of biodiesel including the fact that it is produced from a renewable resource, its biodegradability, and its potential beneficial effects on exhaust emissions. Transient exhaust emissions from three modern diesel engines were measured during this study, both with and without an oxidation catalyst. Emissions were characterized with neat biodiesel and with a blend of biodiesel and conventional diesel fuel. Regulated emissions and performance data are presented in this paper, while the results of a detailed chemical characterization of exhaust emissions are presented in a companion paper. The use of biodiesel resulted in lower emissions of unburned hydrocarbons, carbon monoxide, and particulate matter, with some increase in emissions of oxides of nitrogen on some engines.