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Selective catalyst reduction (SCR) using cordierite honeycomb substrate is generally used as a DeNOx catalyst for diesel engines exhaust in both on-road and commercial off-highway vehicles to meet today’s worldwide emission regulations. Worldwide NOx emission regulations will become stricter, as represented by CARB2027 and EuroVII. Technologies which can achieve further lower NOx emissions are required. Recently, several technologies, like increased SCR catalyst loading amount on honeycomb substrates, and additional SCR catalyst volume in positions closer to the engine are being considered to achieve ultra-low NOx emissions. However, undesirable pressure drop increase and enlarging after treatment systems will be caused by adopting these technologies. Therefore, optimization of the material and honeycomb cell structure for SCR is inevitable to achieve ultra-low NOx emissions, while minimizing any system drawbacks.

Ammonia Selective Catalytic Reduction (SCR) is adapted for a variety of applications to control nitrogen oxides (NOx) in diesel engine exhaust. The most commonly used catalyst for SCR in established markets is Cu-Zeolite (CuZ) due to excellent NOx conversion and thermal durability. However, most applications in emerging markets and certain applications in established markets utilize vanadia SCR. The operating temperature is typically maintained below 550°C to avoid vanadium sublimation due to active regeneration of the diesel particulate filter (DPF), or some OEMs may eliminate the DPF because they can achieve particulate matter (PM) standard with engine tuning. Further improvement of vanadia SCR durability and NOx conversion at low exhaust gas temperatures will be required in consideration of future emission standards.

Ammonia Selective Catalytic Reduction (SCR) is a key emission control component utilized in diesel engine applications for NOx reduction. There are several types of SCR catalyst currently in the market: Cu-Zeolite, Fe-Zeolite and Vanadia. Diesel vehicle and engine manufacturers down select their production SCR catalyst primarily based on vehicle exhaust gas temperature operation, ammonia dosing strategy, fuel quality, packaging envelope and cost. For Vanadia SCR, the operating temperature is normally controlled below 550oC to avoid vanadium sublimation. In emerging markets, the Vanadia SCR is typically installed alone or downstream of the DOC with low exhaust gas temperature exposure. Vanadia SCR is also utilized in some European applications with passive DPF soot regeneration. However, further improvement of Vanadia SCR NOx conversion at low exhaust gas temperatures will be required to meet future emission regulations (i.e.: HDD Phase 2 GHG).

Today the Ammonia Selective Catalytic Reduction (SCR) system with good NOx conversion is the emission technology of choice for diesel engines globally. High NOx conversion SCR systems combined with optimized engine calibration not only address the stringent NOx emission limits which have been introduced or are being considered for later this decade, but also reduce CO2 emissions required by government regulations and the increase in fuel economy required by end-users. Reducing the packaging envelope of today's SCR systems, while retaining or improving NOx conversion and pressure drop, is a key customer demand. High SCR loadings ensure high NOx conversion at very low temperatures. To meet this performance requirement, a High Porosity Substrate which minimizes the pressure drop impact, was introduced in SAE Paper 2012-01-1079 [1], [2], [3].

Ammonia Selective Catalytic Reduction (SCR) and Lean NOx Trap (LNT) systems are key technologies to reduce NOx emission for diesel on-highway vehicles to meet worldwide tighter emission regulations. In addition DeNOx catalysts have already been applied to several commercial off-road applications. Adding the DeNOx catalyst to existing Diesel Oxidation Catalyst (DOC) and Diesel Particulate Filter (DPF) emission control system requires additional space and will result in an increase of emission system back pressure. Therefore it is necessary to address optimizing the DeNOx catalyst in regards to back pressure and downsizing. Recently, extruded zeolite for DeNOx application has been considered. This technology improves NOx conversion at low temperature due to the high catalyst amount. However, this technology has concerned about strength and robustness, because the honeycomb body is composed of catalyst.

As emissions regulations are becoming more stringent, various efforts to improve emission performance have been carried out in different areas including the honeycomb structure of catalytic converters. This report describes the development of a simulation tool to predict emission performance and simulation results for different cell structures. The simulation model was developed based on global kinetic chemical reaction model [1]. Having tuned the reaction parameters through a light-off test and estimated oxygen storage capacity through an oxygen storage test, we ultimately tuned the model in a vehicle test (with Bags 1 and 2, FTP 75). As a result, the simulated cumulative tailpipe emissions are within ±25 percent of the test results. Parameter analyses indicate that the amount of emissions decreased as the density of cells increased and that the amount of emissions also decreased the thinner the wall thicknesses were.