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Ethanol can be converted into a 1:1:1 mixture of H2, CO, and CH4 at 300°C using a copper-nickel catalyst, a process known as “low-temperature ethanol reforming.” The hydrogen content of this mixture enables an engine to operate lean or with high levels of EGR, improving fuel economy and emissions. An onboard ethanol reformer- a catalyst module providing heat exchange with exhaust-was recently reported and shown to exhibit stable high conversion of ethanol driven by exhaust heat. This paper describes the successful integration and operation of a Ford 3.5L 3 TiVCT flex-fuel engine with a compact reformer and auxiliary hardware, fueled by E85. The system constitutes an integrated power system suitable for vehicle integration. The engine was operated on a mixture of E85 and reformate using a stoichiometric air-fuel ratio with internal EGR at a 12:1 compression ratio.

It has been previously reported that ethanol can be reformed at around 300°C to a mixture of hydrogen, carbon monoxide, and methane using copper-plated nickel catalyst. This low reforming temperature enables heat to be supplied from the engine exhaust. Single-cylinder engine testing demonstrated that this gaseous mixture of "ethanol reformate" enhances engine combustion and part load dilution capability, which decreases fuel consumption while also reducing feedgas NOx emissions. In addition, excellent cold start capability with significantly reduced hydrocarbon emissions was observed. Thus, ethanol reformate has the potential to address two major barriers to wider use of ethanol as an engine fuel: ethanol's low heating value per volume and higher hydrocarbon emissions at startup relative to gasoline. In this study, the dilute capability of a multi-cylinder engine was assessed using a mixture of 50% reformate and 50% E85 on a mass basis at several key part load operating points.

Two major barriers to wider use of ethanol as an engine fuel are ethanol's low heating value per volume relative to gasoline and higher hydrocarbon emissions at startup. Ethanol provides about one-third lower fuel economy than gasoline on a volumetric basis if the two fuels are utilized with equal efficiency, making ethanol less attractive to consumers. In addition, it is difficult to meet emissions standards such as SULEV when using E85 or hydrous ethanol, because ethanol's low volatility and high heat of vaporization compared to gasoline result in incomplete combustion when the engine is cold. A catalyst consisting of a copper-plated nickel sponge has recently been developed that enables ethanol to be reformed at around 300°C to a mixture of hydrogen (H₂), carbon monoxide (CO), and methane (CH₄). This low reforming temperature enables heat to be supplied from the engine exhaust.

The use of hydrogen as a fuel supplement for lean-burn engines at higher compression ratios has been studied extensively in recent years, with good promise of performance and efficiency gains. With the advances in reformer technology, the use of a gaseous fuel stock, comprising of substantially higher fractions of hydrogen and other flammable reformate species, could provide additional improvements. This paper presents the performance and emission characteristics of a gas mixture of equal volumes of hydrogen, CO, and methane. It has recently been reported that this gas mixture can be produced by reforming of ethanol at comparatively low temperature, around 300C. Experiments were performed on a 1.8-liter passenger-car Nissan engine modified for single-cylinder operation. Special pistons were made so that compression ratios ranging from CR= 9.5 to 17 could be used. The lean limit was extended beyond twice stoichiometric (up to lambda=2.2).