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There are a few different ways in which biofuels can be sourced, with the most popular coming from agricultural sources. An alternative approach is to utilize biowaste. An estimated 20 million dry tons of volatile organic compounds, or biowaste, is annually deposited in US municipal wastewaters. Most of this biowaste energy content is not recovered and, as a result, the biowaste could be a massive potential source of renewable energy. Biocrude diesel is converted from wet biowaste via hydrothermal liquefaction (HTL). Three types of feedstocks (algae, swine manure, and food processing waste) were converted into biocrude oil via HTL. From the previous experiments done in an AVL 5402 single-cylinder diesel engine, it was observed that the presence of 20% of HTL in the blend performed similarly during combustion to pure diesel. By studying these mixtures in a constant volume chamber, these observations could be compared to the results in the diesel engine.

Bio-butanol has been considered as a promising alternative fuel for internal combustion engines due to its advantageous physicochemical properties. However, the further development of bio-butanol is inhibited by its high recovery cost and low production efficiency. Hence, the goal of this study is to evaluate two upstream products from different fermentation processes of bio-butanol, namely acetone-butanol-ethanol (ABE) and isopropanol-butanol-ethanol (IBE), as alternative fuels for diesel. The experimental comparison is conducted on a single-cylinder and common-rail diesel engine under various main injection timings (MIT) and equivalent engine load (EEL) conditions. The experimental results show that ABE and IBE significantly affect the combustion phasing. The start of combustion (SOC) is retarded when ABE and IBE are mixed with diesel. Furthermore, the ABE/IBE-diesel blends are more sensitive to the changes in MIT compared with that of pure diesel.

Recent research has shown that butanol, instead of ethanol, has the potential of introducing a more suitable blend in diesel engines. This is because butanol has properties similar to current transportation fuels in comparison to ethanol. However, the main downside is the high cost of the butanol production process. Acetone-butanol-ethanol (ABE) is an intermediate product of the fermentation process of butanol production. By eliminating the separation and purification processes, using ABE directly in diesel blends has the potential of greatly decreasing the overall cost for fuel production. This could lead to a vast commercial use of ABE-diesel blends on the market. Much research has been done in the past five years concerning spray and combustion processes of both neat ABE and ABE-diesel mixtures. Additionally, different compositions of ABE mixtures had been characterized with a similar experimental approach.

Performance and emissions of a common-rail production diesel engine fueled with soybean-derived biodiesel was investigated. The work was broken down into two categories. First, adjustment of injection timing and EGR ratio was investigated as a means to reduce NOx emissions to levels comparable with those obtained when using pure diesel fuel. Next, simultaneous reduction of NOx and soot emissions was investigated using high rates of EGR combined with late injection timings to approach the low-temperature combustion regime. Results from the first part of the study indicate that optimization of engine control parameters for use with biodiesel can be beneficial to performance and emissions. It was found that adjusting the engine's MAF setpoint table to reflect the difference in stoichiometric air-fuel ratio between diesel and biodiesel brought NOx emissions to comparable or lower levels.

The KIVA-3V code, developed by Los Alamos National Laboratory, with modifications that improve its capability with biodiesel simulations was used to model the operation of an HSDI engine using blends of soybean biodiesel and diesel. Biodiesel and their blends with diesel are frequently used to reduce emissions from diesel engines, although previous studies showed that biodiesel may increase NOx emission. The paradox may be resolved by running the engine in low temperature combustion mode with biodiesel/diesel blends, as low temperature combustion simultaneously reduced NOx and soot. The modified KIVA code predicts the major combustion characteristics: peak combustion pressure, heat release rate and ignition timing accurately when compared with experimental measurements. It also correctly predicts the trend of NOx emissions. It was observed that the cylinder temperature distribution has a strong effect on emission levels.

Biodiesel fuels and their blends with diesel are often used to reduce emissions from diesel engines. However, biodiesel has been shown to increase the NOx emissions. Operating a compression ignition engine in low-temperature combustion mode as well as using multiple injections can reduce NOx emissions. Experimental data for biodiesel are compared to those for diesel to show the effect of the biodiesel on the peak pressure, temperature, and emissions. Accurate prediction of biodiesel properties, combined with the KIVA 3V code, is used to investigate the combustion of biodiesel. The volume fraction of the cylinder that has temperatures greater than 2200 K is shown to directly affect the production of oxides of nitrogen. Biodiesel is shown to burn faster during the combustion events, though the ignition delay is often longer for biodiesel compared to diesel.

The use of substances other than petroleum based fuels for power sources is not a new concept. Prior to the advent of petroleum fueled vehicles numerous other substances were used to create mobile sources of power. As the world's petroleum supply dwindles, alternative fuel sources are sought after to replace petroleum fuels. Many industries are particularly interested in the development of renewable fuel sources, or biologically derived fuel sources, which includes ethanol. The use of No. 2 diesel as well as many alternative fuels in compression ignition engines result in injector coking. Injector coking can severely limit engine performance by limiting the amount of fuel delivered to the combustion chamber and altering the spray pattern. Injector tip coking is also one of the most sensitive measures of diesel fuel quality [1]. A machine vision system was implemented to quantify injector coking accumulation when a compression ignition engine was fueled with oxydiesel.